Pyrazole derivative

ABSTRACT

A pyrazole derivative having the following formula stru-1: 
     
       
         
         
             
             
         
       
     
     The pyrazole derivative is used for prevention and control of pests.

FIELD OF THE INVENTION

The present invention relates to the field of agricultural insecticides and acaricides, and in particular to a pyrazole derivative.

BACKGROUND OF THE INVENTION

Presently, due to long-term use of pesticides, pests and insects produce resistance, resulting in a significant increase in the use of pesticides and serious damage to the environment. Therefore, it is required to continuously discover high-efficiency new pesticides with new mechanism of action, for example, new pesticides with higher activity against insects and pests, bacteria or acarids. Among the existing acaricide pesticides, most of pesticides can only control one of the three stages of eggs, nymphs and adult mites. It will be of significance if we can research and develop acaricides that have control effects on three stages of acarids.

The PCT Patent Application WO 01/68589 discloses heterocyclic acrylonitrile ether compounds, and the following compounds 8-1, 8-2, 8-3 and 8-4 are disclosed on page 71 in the Description.

The pyrazole derivatives described herein are not disclosed in the prior art.

SUMMARY OF THE INVENTION

The present invention provides a pyrazole derivative having the following formula stru-1:

wherein:

R1, R2, R3, R4, R5 are independently selected from hydrogen, halogen, nitro, nitrile, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio, C₁-C₂₀ alkylsulfoxide, C₁-C₂₀ alkylsulfone, C₁-C₂₀ alkylsulfonate, C₁-C₂₀ alkyl carboxylic ester, C₁-C₂₀ alkyl acyl, C₁-C₂₀ haloalkyl acyl;

-   -   R6 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₂₀         alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀         halocycloalkyl, C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀         alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy,         C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio, phenyl substituted by at         least one of hydrogen, halogen, nitro, cyano, C₁-C₂ alkyl,         C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl,         C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀         haloalkylthio and C₁-C₂₀ alkylsulfone, pyridyl, pyrazolyl,         thienyl, furyl or thiazolyl substituted by at least one of         hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl,         C₃-C₂₀ cycloalkyl. C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀         haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀         alkylsulfone;     -   R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₂₀         alkyl, C₁-C₂₀ haloalkyl, C₁-C₂ alkoxymethylene;     -   R8 is selected from hydrogen C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl,         C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀         alkoxymethylene, phenyl substituted by at least one of hydrogen,         halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂ haloalkyl, C₃-C₂₀         cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀         haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀         alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl         substituted by at least one hydrogen, halogen, nitro, cyano         C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀         halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂ haloalkoxy, C₁-C₂₀         alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone;     -   R9 is selected from hydrogen, halogen. nitro C₁-C₂₀ alkyl,         C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl,         C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀         haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio,         C₁-C₂₀ haloalkylthio, C₁-C₂₀ alkylsulfone, phenyl substituted by         at least one of hydrogen, halogen. nitro, cyano, C₁-C₂ alkyl,         C₁-C₂ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl,         C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀         haloalkylthio and C₁-C₂₀ alkylsulfone, pyridyl, pyrazolyl,         thienyl, furyl or thiazolyl substituted by at least one of         hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl,         C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀         haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀         alkylsulfone;     -   L is selected from oxygen, sulfur. methylene, nitrogen;     -   Q is selected from oxygen, sulfur;     -   R10 is selected from hydrogen, halogen. nitro, C₁-C₂₀ alkyl,         C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl,         C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀         haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio,         C₁-C₂₀ haloalkylthio, C₁-C₂₀ alkyl carboxylic ester, phenyl         substituted by at least one of hydrogen, halogen, nitro, cyano,         C₁-C₂ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀         halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀         alkylthio and C₁-C₂₀ haloalkylthio, pyridyl, pyrazolyl, thienyl,         furyl or thiazolyl substituted by at least one of hydrogen,         halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀         cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀         haloalkoxy, C₁-C₂₀ alkylthio and C₁-C₂₀ haloalkylthio.

In the pyrazole derivatives represented by the formula stru-1 provided in the present invention, substituents R1, R2, R3, R4, R5 are independently selected from hydrogen, halogen, nitro, nitrile, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₂-C₂₀ alkenyl, C₂-C₂a haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio, C₁-C₂ alkylsulfoxide, C₁-C₂₀ alkylsulfone, C₁-C₂ alkylsulfonate, C₁-C₂₀ alkyl carboxylic ester, C₁-C₂₀ alkyl acyl, C₁-C₂₀ haloalkyl acyl.

Preferably, the substituents R1, R2, R3, R4, R5 are independently selected from hydrogen, halogen, nitro, nitrile C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₂-C₁₀ alkenyl, C₂-C₁₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₁₀ haloalkynyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio, C₁-C₁₀ alkylsulfoxide, C₁-C₁₀ alkylsulfone, C₁-C₁₀ alkylsulfonate, C₁-C₁₀ alkyl carboxylic ester, C₁-C₁₀ alkyl acyl, C₁-C₁₀ haloalkyl acyl.

Further preferably, the substituents R1, R2, R3, R4, R5 are independently selected from hydrogen, halogen, nitro, nitrile, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ alkylsulfoxide, C₁-C₆ alkylsulfone, C₁-C₆ alkylsulfonate, C₁-C₆ alkyl carboxylic ester, C₁-C₆ alkyl acyl, C₁-C₆ haloalkyl acyl.

Still further preferably, the substituents R, R2, R3, R4, R5 are independently selected from hydrogen, fluorine, chlorine, bromine, nitro, nitrile, methyl, ethyl, isopropyl, tert-butyl, trifluoromethyl, methoxy, ethoxy, trifluoromethoxy, difluoromethoxy, difluoroethoxy, methylthio, trifluoromethylthio, trifluoroethylthio, methylsulfonyl, methylsulfonate.

In the pyrazole derivatives represented by the formula stru-1 provided in the present invention, the substituent R6 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂ haloalkylthio, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen. nitro, cyano C₁-C₂ alkyl, C₁-C₂ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone.

Preferably, the substituent R6 is selected from hydrogen, halogen. nitro, nitrile, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₂-C₁₀ alkenyl, C₂-C₁₀ haloalkenyl, C₂-C₁₀ alkynyl, C₂-C₁₀ haloalkynyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone. The compound may be in the form of E, Z or a mixture of E and Z;

Further preferably, the substituent R6 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone.

Still further preferably, the substituent R6 is selected from hydrogen, fluorine, chlorine, bromine, nitro, nitrile, methyl, ethyl, isopropyl, cyclopropyl, methoxy, ethoxy, trifluoromethyl, difluoromethyl, p-chlorophenyl, P-fluorophenyl.

In the pyrazole derivatives represented by the formula stru-1 provided in the present invention, substituent R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₁-C₂₀ alkoxymethylene.

Preferably, the substituent R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₁-C₁₀ alkoxymethylene.

Further preferably, the substituent R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₁-C₆ alkoxymethylene.

Still further preferably, the substituent R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₅ alkyl, C₁-C₅ haloalkyl, C₁-C₅ alkoxymethylene.

In the pyrazole derivatives represented by the formula stru-1 provided in the present invention. substituent R8 is selected from hydrogen, C₁-C₂ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxymethylene, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂ haloalkyl, C₃-C₂ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one substituted pyridyl, pyrazolyl, thienyl, furyl or thiazolyl selected from the group consisting of hydrogen, halogen. nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone.

Preferably, the substituent R8 is selected from hydrogen, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxymethylene, phenyl substituted by at least one of hydrogen, halogen. nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen. nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone.

Further preferably, the substituent R8 is selected from hydrogen, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxymethylene, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone.

Still further preferably, the substituent R8 is selected from hydrogen, methyl, ethyl, monofluoromethyl, difluoromethyl, trifluoromethyl, methoxymethylene, ethoxymethylene.

In the pyrazole derivatives represented by the formula stru-1 provided in the present invention, substituent R9 is selected from hydrogen, halogen, nitro, C₁-C₂ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio, C₁-C₂₀ alkylsulfone, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone.

Preferably, the substituent R9 is selected from hydrogen, halogen, nitro, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₂-C₁₀ alkenyl, C₂-C₁₀ haloalkenyl, C₂-C₁₀alkynyl, C₂-C₁₀ haloalkynyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio, C₁-C₁₀ alkylsulfone, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone.

Further preferably, the substituent R9 is selected from hydrogen, halogen, nitro, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ alkylsulfone, phenyl substituted by at least one of hydrogen, halogen. nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone.

Still further preferably, the substituent R9 is selected from hydrogen, fluorine, chlorine, bromine, nitro, methyl, ethyl, propyl, isopropyl, difluoromethyl, cyclopropyl, methylthiomethylene, phenyl, p-chlorophenyl, p-fluorophenyl, benzyl.

In the pyrazole derivatives represented by the formula stru-1 provided in the present invention, substituent L is selected from oxygen, sulfur, methylene, nitrogen.

Preferably, the substituent L is selected from oxygen, sulfur, methylene.

In the pyrazole derivatives represented by the formula stru-1 provided in the present invention, substituent Q is selected from oxygen, sulfur.

In the pyrazole derivatives represented by the formula stru-1 provided in the present invention, substituent R10 is selected from hydrogen, halogen, nitro, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio, C₁-C₂₀ alkyl carboxylic ester, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio and C₁-C₂₀ haloalkylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂ alkyl, C₁-C₂ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio and C₁-C₂₀ haloalkylthio.

Preferably, the substituent R10 is selected from hydrogen, halogen, nitro, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkenyl, C₂-C₁₀ haloalkenyl, C₂-C₁₀ alkynyl, C₂-C₁₀ haloalkynyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio, C₁-C₁₀ alkyl carboxylic ester, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio and C₁-C₁₀ haloalkylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₁₀ alkylthio and C₁-C₁₀ haloalkylthio.

Further preferably, the substituent R10 is selected from hydrogen, halogen, nitro, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ alkyl carboxylic ester, phenyl substituted by at least one of hydrogen, halogen. nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio and C₁-C₆ haloalkylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₁-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio and C₁-C₆ haloalkylthio.

Still further preferably, the substituent R10 is selected from hydrogen, fluorine, chlorine, nitro, C₁-C₆ alkyl, C₃—C cycloalkyl, C₃-C₆ haloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ methyl alkyl carboxylate. C₁-C₆ ethyl carboxylic acid ethyl ester, phenyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, trifluoromethyl, methoxy. ethoxy, trifluoroethoxy, and methylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl. ethyl, trifluoromethyl, methoxy, ethoxy, trifluoroethoxy, and methylthio.

For the pyrazole derivatives represented by the formula stru-1 provided herein, as a preferred embodiment, in the formula stru-1:

R1, R2, R3, R4, R5 are independently selected from hydrogen, fluorine, chlorine, bromine, nitro, nitrile, methyl, ethyl, isopropyl, tert-butyl, trifluoromethyl, methoxy, ethoxy, trifluoromethoxy, difluoromethoxy, difluoroethoxy, methylthio, trifluoromethylthio, trifluoroethylthio, methylsulfonyl, methylsulfonate;

R6 is selected from hydrogen, fluorine, chlorine, bromine, nitro, nitrile, methyl, ethyl, isopropyl, cyclopropyl, trifluoromethyl, difluoromethyl, methoxy, ethoxy, p-chlorophenyl, p-fluorophenyl;

R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₅ alkyl, C₁-C₅ haloalkyl, C₁-C₅ alkoxymethylene;

R8 is selected from methyl, ethyl;

R9 is selected from hydrogen, fluorine, chlorine, bromine. nitro, methyl, ethyl, propyl, isopropyl, difluoromethyl, cyclopropyl, methylthiomethylene, phenyl, p-chlorophenyl, p-fluorophenyl, benzyl:

L is selected from oxygen, sulfur, methylene:

Q is selected from oxygen, sulfur:

R10 is selected from hydrogen, fluorine, chlorine, nitro, C₁-C₆ alkyl, C₃-C₆ cycloalkyl, C₃-C₆ haloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ methyl alkyl carboxylate. C₁-C₆, ethyl carboxylic acid ethyl ester, phenyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, trifluoroethoxy, and methylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, trifluoroethoxy, and methylthio.

For the pyrazole derivatives represented by the formula stru-1 provided herein, as another preferred embodiment, in the formula stru-1:

R1, R2, R4, R5 are selected from hydrogen;

R3 is selected from t-butyl;

R6 is selected from hydrogen, fluorine, chlorine, bromine. nitro, nitrile, methyl, ethyl, isopropyl. cyclopropyl. trifluoromethyl, difluoromethyl. methoxy, ethoxy, p-chlorophenyl, p-fluorophenyl;

R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₅ alkyl, C₁-C₅ haloalkyl, C₁-C₅ alkoxymethylene:

R8 is selected from methyl, ethyl;

R9 is selected from hydrogen, fluorine, chlorine, bromine, nitro, methyl, ethyl, propyl, isopropyl, difluoromethyl, cyclopropyl, methylthiomethylene, phenyl, p-chlorophenyl, p-fluorophenyl, benzyl:

L is selected from oxygen. sulfur, methylene:

Q is selected from oxygen, sulfur;

R10 is selected from hydrogen, fluorine, chlorine, nitro, C₁-C₆ alkyl, C₃-C₆ cycloalkyl, C₃-C₆ haloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ methyl alkyl carboxylate, C₁-C₆ ethyl carboxylic acid ethyl ester, phenyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, methoxy, ethoxy, trifluoromethyl, trifluoroethoxy, and methylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, methoxy, ethoxy, trifluoromethyl, trifluoroethoxy, and methylthio.

For pyrazole derivatives represented by the formula stru-1 provided herein, as the most preferred embodiment, the pyrazole derivatives are selected from at least one of the compounds represented by the following structural formula:

For pyrazole derivatives represented by the above numbers, preferably, the compound is an E-pyrazole derivative, that is, E-isomer.

The pyrazole derivatives represented by the formula stru-1 provided herein comprise at least one selected from the group consisting of an E-type pyrazole derivative and a Z-type pyrazole derivative. When the pyrazole derivative comprises an E-type pyrazole derivative and a Z-type pyrazole derivative, the E-type pyrazole derivative and the Z-type pyrazole derivative may be present in any ratio.

For pyrazole derivatives represented by the formula stru-1 provided herein when substituents R1, R2, R4, and R5 are hydrogen and Q is oxygen, as an example, when the pyrazole derivative represented by the formula stru-1 is an E-type compound. the pyrazole derivative represented by the formula stru-1 may be a compound shown in Table 1.

TABLE 1 No. R3 R9 R8 R6 R7 L-R10 1. (CH₃)₃C H CH₃ CH₃ H CH₃ 2. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂ 3. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂CH₂ 4. (CH₃)₃C H CH₃ CH₃ H (CH₃)₂CH 5. (CH₃)₃C H CH₃ CH₃ H (CH₃)₃C 6. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂CH₂CH₂ 7. (CH₃)₃C H CH₃ CH₃ H (CH₃)₂CHCH₂ 8. (CH₃)₃C H CH₃ CH₃ H CH₃OCH₂ 9. (CH₃)₃C H CH₃ CH₃ H

10. (CH₃)₃C H CH₃ CH₃ H CH₃SCH₂ 11. (CH₃)₃C H CH₃ CH₃ H

12. (CH₃)₃C H CH₃ CH₃ H FCH₂ 13. (CH₃)₃C H CH₃ CH₃ H F₃C 14. (CH₃)₃C H CH₃ CH₃ H C₆H₅ 15. (CH₃)₃C H CH₃ CH₃ H C₆H₅CH₂ 16. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂(CH₃)₂C 17. (CH₃)₃C H CH₃ CH₃ H CH2═CH 18. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂OCH₂ 19. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂SCH₂ 20. (CH₃)₃C H CH₃ CH₃ H

21. (CH₃)₃C H CH₃ CH₃ H

22. (CH₃)₃C H CH₃ CH₃ H CF₃CH₂SCH₂ 23. (CH₃)₃C H CH₃ CH₃ H ClCH₂CH₂ 24. (CH₃)₃C H CH₃ CH₃ H ClCH₂CH₂CH₂ 25. (CH₃)₃C H CH₃ CH₃ H NCCH2 26. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃ 27. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂ 28. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂CH₂ 29. (CH₃)₃C CH₃ CH₃ CH₃ H (CH₃)₂CH 30. (CH₃)₃C CH₃ CH₃ CH₃ H (CH₃)₃C 31. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂CH₂CH₂ 32. (CH₃)₃C CH₃ CH₃ CH₃ H (CH₃)₂CHCH₂ 33. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃OCH₂ 34. (CH₃)₃C CH₃ CH₃ CH₃ H

35. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃SCH₂ 36. (CH₃)₃C CH₃ CH₃ CH₃ H

37. (CH₃)₃C CH₃ CH₃ CH₃ H FCH₂ 38. (CH₃)₃C CH₃ CH₃ CH₃ H F₃C 39. (CH₃)₃C CH₃ CH₃ CH₃ H C₆H₅ 40. (CH₃)₃C CH₃ CH₃ CH₃ H C₆H₅CH₂ 41. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂(CH₃)₂C 42. (CH₃)₃C CH₃ CH₃ CH₃ H CH2═CH 43. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂OCH₂ 44. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂SCH₂ 45. (CH₃)₃C CH₃ CH₃ CH₃ H

46. (CH₃)₃C CH₃ CH₃ CH₃ H

47. (CH₃)₃C CH₃ CH₃ CH₃ H CF₃CH₂SCH₂ 48. (CH₃)₃C CH₃ CH₃ CH₃ H ClCH₂CH₂ 49. (CH₃)₃C CH₃ CH₃ CH₃ H ClCH₂CH₂CH₂ 50. (CH₃)₃C CH3 CH₃ CH₃ H NCCH2 51. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃ 52. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂ 53. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂CH₂ 54. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H (CH₃)₂CH 55. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H (CH₃)₃C 56. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂CH₂CH₂ 57. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H (CH₃)₂CHCH₂ 58. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃OCH₂ 59. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H

60. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃SCH₂ 61. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H

62. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H FCH₂ 63. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H F₃C 64. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H C₆H₅ 65. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H C₆H₅CH₂ 66. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂(CH₃)₂C 67. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH2═CH 68. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂OCH₂ 69. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂SCH₂ 70. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H

71. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H

72. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CF₃CH₂SCH₂ 73. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H ClCH₂CH₂ 74. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H ClCH₂CH₂CH₂ 75. (CH₃)₃C CH3CH2 CH₃ CH₃ H NCCH2 76. (CH₃)₃C H CH₃ CH₃ Cl CH₃ 77. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂ 78. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂CH₂ 79. (CH₃)₃C H CH₃ CH₃ Cl (CH₃)₂CH 80. (CH₃)₃C H CH₃ CH₃ Cl (CH₃)₃C 81. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂CH₂CH₂ 82. (CH₃)₃C H CH₃ CH₃ Cl (CH₃)₂CHCH₂ 83. (CH₃)₃C H CH₃ CH₃ Cl CH₃OCH₂ 84. (CH₃)₃C H CH₃ CH₃ Cl

85. (CH₃)₃C H CH₃ CH₃ Cl CH₃SCH₂ 86. (CH₃)₃C H CH₃ CH₃ Cl

87. (CH₃)₃C H CH₃ CH₃ Cl FCH₂ 88. (CH₃)₃C H CH₃ CH₃ Cl F₃C 89. (CH₃)₃C H CH₃ CH₃ Cl C₆H₅ 90. (CH₃)₃C H CH₃ CH₃ Cl C₆H₅CH₂ 91. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂(CH₃)₂C 92. (CH₃)₃C H CH₃ CH₃ Cl CH2═CH 93. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂OCH₂ 94. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂SCH₂ 95. (CH₃)₃C H CH₃ CH₃ Cl

96. (CH₃)₃C H CH₃ CH₃ Cl

97. (CH₃)₃C H CH₃ CH₃ Cl CF₃CH₂SCH₂ 98. (CH₃)₃C H CH₃ CH₃ Cl ClCH₂CH₂ 99. (CH₃)₃C H CH₃ CH₃ Cl ClCH₂CH₂CH₂ 100. (CH₃)₃C H CH₃ CH₃ Cl NCCH2 101. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃ 102. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂ 103. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂CH₂ 104. (CH₃)₃C CH₃ CH₃ CH₃ Cl (CH₃)₂CH 105. (CH₃)₃C CH₃ CH₃ CH₃ Cl (CH₃)₃C 106. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂CH₂CH₂ 107. (CH₃)₃C CH₃ CH₃ CH₃ Cl (CH₃)₂CHCH₂ 108. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃OCH₂ 109. (CH₃)₃C CH₃ CH₃ CH₃ Cl

110. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃SCH₂ 111. (CH₃)₃C CH₃ CH₃ CH₃ Cl

112. (CH₃)₃C CH₃ CH₃ CH₃ Cl FCH₂ 113. (CH₃)₃C CH₃ CH₃ CH₃ Cl F₃C 114. (CH₃)₃C CH₃ CH₃ CH₃ Cl C₆H₅ 115. (CH₃)₃C CH₃ CH₃ CH₃ Cl C₆H₅CH₂ 116. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂(CH₃)₂C 117. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH2═CH 118. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂OCH₂ 119. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂SCH₂ 120. (CH₃)₃C CH₃ CH₃ CH₃ Cl

121. (CH₃)₃C CH₃ CH₃ CH₃ Cl

122. (CH₃)₃C CH₃ CH₃ CH₃ Cl CF₃CH₂SCH₂ 123. (CH₃)₃C CH₃ CH₃ CH₃ Cl ClCH₂CH₂ 124. (CH₃)₃C CH₃ CH₃ CH₃ Cl ClCH₂CH₂CH₂ 125. (CH₃)₃C CH3 CH₃ CH₃ Cl NCCH2 126. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃ 127. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂ 128. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂CH₂ 129. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl (CH₃)₂CH 130. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl (CH₃)₃C 131. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂CH₂CH₂ 132. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl (CH₃)₂CHCH₂ 133. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃OCH₂ 134. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl

135. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃SCH₂ 136. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl

137. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl FCH₂ 138. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl F₃C 139. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl C₆H₅ 140. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl C₆H₅CH₂ 141. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂(CH₃)₂C 142. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH2═CH 143. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂OCH₂ 144. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂SCH₂ 145. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl

146. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl

147. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CF₃CH₂SCH₂ 148. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl ClCH₂CH₂ 149. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl ClCH₂CH₂CH₂ 150. (CH₃)₃C CH3CH2 CH₃ CH₃ Cl NCCH2 151. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃ 152. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂ 153. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂CH₂ 154. (CH₃)₃C H CH₃ CH₃ CH₃ (CH₃)₂CH 155. (CH₃)₃C H CH₃ CH₃ CH₃ (CH₃)₃C 156. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂CH₂CH₂ 157. (CH₃)₃C H CH₃ CH₃ CH₃ (CH₃)₂CHCH₂ 158. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃OCH₂ 159. (CH₃)₃C H CH₃ CH₃ CH₃

160. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃SCH₂ 161. (CH₃)₃C H CH₃ CH₃ CH₃

162. (CH₃)₃C H CH₃ CH₃ CH₃ FCH₂ 163. (CH₃)₃C H CH₃ CH₃ CH₃ F₃C 164. (CH₃)₃C H CH₃ CH₃ CH₃ C₆H₅ 165. (CH₃)₃C H CH₃ CH₃ CH₃ C₆H₅CH₂ 166. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂(CH₃)₂C 167. (CH₃)₃C H CH₃ CH₃ CH₃ CH2═CH 168. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂OCH₂ 169. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂SCH₂ 170. (CH₃)₃C H CH₃ CH₃ CH₃

171. (CH₃)₃C H CH₃ CH₃ CH₃

172. (CH₃)₃C H CH₃ CH₃ CH₃ CF₃CH₂SCH₂ 173. (CH₃)₃C H CH₃ CH₃ CH₃ ClCH₂CH₂ 174. (CH₃)₃C H CH₃ CH₃ CH₃ ClCH₂CH₂CH₂ 175. (CH₃)₃C H CH₃ CH₃ CH₃ NCCH2 176. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃ 177. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂ 178. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂CH₂ 179. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ (CH₃)₂CH 180. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ (CH₃)₃C 181. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂CH₂CH₂ 182. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ (CH₃)₂CHCH₂ 183. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃OCH₂ 184. (CH₃)₃C CH₃ CH₃ CH₃ CH₃

185. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃SCH₂ 186. (CH₃)₃C CH₃ CH₃ CH₃ CH₃

187. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ FCH₂ 188. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ F₃C 189. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ C₆H₅ 190. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ C₆H₅CH₂ 191. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂(CH₃)₂C 192. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH2═CH 193. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂OCH₂ 194. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂SCH₂ 195. (CH₃)₃C CH₃ CH₃ CH₃ CH₃

196. (CH₃)₃C CH₃ CH₃ CH₃ CH₃

197. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CF₃CH₂SCH₂ 198. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ ClCH₂CH₂ 199. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ ClCH₂CH₂CH₂ 200. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ NCCH2 201. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃ 202. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂ 203. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂CH₂ 204. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ (CH₃)₂CH 205. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ (CH₃)₃C 206. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂CH₂CH₂ 207. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ (CH₃)₂CHCH₂ 208. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃OCH₂ 209. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃

210. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃SCH₂ 211. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃

212. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ FCH₂ 213. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ F₃C 214. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ C₆H₅ 215. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ C₆H₅CH₂ 216. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂(CH₃)₂C 217. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH2═CH 218. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂OCH₂ 219. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂SCH₂ 220. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃

221. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃

222. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CF₃CH₂SCH₂ 223. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ ClCH₂CH₂ 224. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ ClCH₂CH₂CH₂ 225. (CH₃)₃C CH3CH2 CH₃ CH₃ CH₃ NCCH2 226. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃ 227. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂ 228. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂CH₂ 229. (CH₃)₃C H CH₃CH₂ CH₃ H (CH₃)₂CH 230. (CH₃)₃C H CH₃CH₂ CH₃ H (CH₃)₃C 231. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂CH₂CH₂ 232. (CH₃)₃C H CH₃CH₂ CH₃ H (CH₃)₂CHCH₂ 233. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃OCH₂ 234. (CH₃)₃C H CH₃CH₂ CH₃ H

235. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃SCH₂ 236. (CH₃)₃C H CH₃CH₂ CH₃ H

237. (CH₃)₃C H CH₃CH₂ CH₃ H FCH₂ 238. (CH₃)₃C H CH₃CH₂ CH₃ H F₃C 239. (CH₃)₃C H CH₃CH₂ CH₃ H C₆H₅ 240. (CH₃)₃C H CH₃CH₂ CH₃ H C₆H₅CH₂ 241. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂(CH₃)₂C 242. (CH₃)₃C H CH₃CH₂ CH₃ H CH2═CH 243. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂OCH₂ 244. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂SCH₂ 245. (CH₃)₃C H CH₃CH₂ CH₃ H

246. (CH₃)₃C H CH₃CH₂ CH₃ H

247. (CH₃)₃C H CH₃CH₂ CH₃ H CF₃CH₂SCH₂ 248. (CH₃)₃C H CH₃CH₂ CH₃ H ClCH₂CH₂ 249. (CH₃)₃C H CH₃CH₂ CH₃ H ClCH₂CH₂CH₂ 250. (CH₃)₃C H CH3CH2 CH₃ H NCCH2 251. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃ 252. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂ 253. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂CH₂ 254. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H (CH₃)₂CH 255. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H (CH₃)₃C 256. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂CH₂CH₂ 257. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃OCH₂ 258. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃OCH₂ 259. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H

260. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃SCH₂ 261. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H

262. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H FCH₂ 263. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H F₃C 264. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H C₆H₅ 265. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H C₆H₅CH₂ 266. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂(CH₃)₂C 267. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH2═CH 268. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂OCH₂ 269. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂SCH₂ 270. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H

271. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H

272. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CF₃CH₂SCH₂ 273. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H ClCH₂CH₂ 274. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H ClCH₂CH₂CH₂ 275. (CH₃)₃C CH3 CH3CH2 CH₃ H NCCH2 276. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃ 277. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂ 278. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂CH₂ 279. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H (CH₃)₂CH 280. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H (CH₃)₃C 281. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂CH₂CH₂ 282. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H (CH₃)₂CHCH₂ 283. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃OCH₂ 284. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H

285. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃SCH₂ 286. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H

287. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H FCH₂ 288. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H F₃C 289. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H C₆H₅ 290. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H C₆H₅CH₂ 291. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂(CH₃)₂C 292. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH2═CH 293. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂OCH₂ 294. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂SCH₂ 295. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H

296. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H

297. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CF₃CH₂SCH₂ 298. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H ClCH₂CH₂ 299. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H ClCH₂CH₂CH₂ 300. (CH₃)₃C CH3CH2 CH3CH2 CH₃ H NCCH2 301. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃ 302. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂ 303. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂CH₂ 304. (CH₃)₃C H CH₃CH₂ CH₃ Cl (CH₃)₂CH 305. (CH₃)₃C H CH₃CH₂ CH₃ Cl (CH₃)₃C 306. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂CH₂CH₂ 307. (CH₃)₃C H CH₃CH₂ CH₃ Cl (CH₃)₂CHCH₂ 308. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃OCH₂ 309. (CH₃)₃C H CH₃CH₂ CH₃ Cl

310. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃SCH₂ 311. (CH₃)₃C H CH₃CH₂ CH₃ Cl

312. (CH₃)₃C H CH₃CH₂ CH₃ Cl FCH₂ 313. (CH₃)₃C H CH₃CH₂ CH₃ Cl F₃C 314. (CH₃)₃C H CH₃CH₂ CH₃ Cl C₆H₅ 315. (CH₃)₃C H CH₃CH₂ CH₃ Cl C₆H₅CH₂ 316. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂(CH₃)₂C 317. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH2═CH 318. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂OCH₂ 319. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂SCH₂ 320. (CH₃)₃C H CH₃CH₂ CH₃ Cl

321. (CH₃)₃C H CH₃CH₂ CH₃ Cl

322. (CH₃)₃C H CH₃CH₂ CH₃ Cl CF₃CH₂SCH₂ 323. (CH₃)₃C H CH₃CH₂ CH₃ Cl ClCH₂CH₂ 324. (CH₃)₃C H CH₃CH₂ CH₃ Cl ClCH₂CH₂CH₂ 325. (CH₃)₃C H CH3CH2 CH₃ Cl NCCH2 326. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃ 327. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂ 328. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂CH₂ 329. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl (CH₃)₂CH 330. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl (CH₃)₃C 331. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂CH₂CH₂ 332. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl (CH₃)₂CHCH₂ 333. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃OCH₂ 334. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl

335. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃SCH₂ 336. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl

337. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl FCH₂ 338. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl F₃C 339. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl C₆H₅ 340. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl C₆H₅CH₂ 341. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂(CH₃)₂C 342. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH2═CH 343. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂OCH₂ 344. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂SCH₂ 345. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl

346. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl

347. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CF₃CH₂SCH₂ 348. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl ClCH₂CH₂ 349. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl ClCH₂CH₂CH₂ 350. (CH₃)₃C CH3 CH3CH2 CH₃ Cl NCCH2 351. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃ 352. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂ 353. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂CH₂ 354. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl (CH₃)₂CH 355. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl (CH₃)₃C 356. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂CH₂CH₂ 357. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl (CH₃)₂CHCH₂ 358. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃OCH₂ 359. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl

360. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃SCH₂ 361. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl

362. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl FCH₂ 363. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl F₃C 364. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl C₆H₅ 365. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl C₆H₅CH₂ 366. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂(CH₃)₂C 367. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH2═CH 368. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂OCH₂ 369. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂SCH₂ 370. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl

371. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl

372. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CF₃CH₂SCH₂ 373. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl ClCH₂CH₂ 374. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl ClCH₂CH₂CH₂ 375. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl NCCH₂ 376. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃ 377. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂ 378. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂ 379. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ (CH₃)₂CH 380. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ (CH₃)₃C 381. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂CH₂ 382. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ (CH₃)₂CHCH₂ 383. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃OCH₂ 384. (CH₃)₃C H CH₃CH₂ CH₃ CH₃

385. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃SCH₂ 386. (CH₃)₃C H CH₃CH₂ CH₃ CH₃

387. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ FCH₂ 388. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ F₃C 389. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ C₆H₅ 390. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ C₆H₅CH₂ 391. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂(CH₃)₂C 392. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH2═CH 393. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂OCH₂ 394. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂SCH₂ 395. (CH₃)₃C H CH₃CH₂ CH₃ CH₃

396. (CH₃)₃C H CH₃CH₂ CH₃ CH₃

397. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CF₃CH₂SCH₂ 398. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ ClCH₂CH₂ 399. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ ClCH₂CH₂CH₂ 400. (CH₃)₃C H CH3CH2 CH₃ CH₃ NCCH2 401. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃ 402. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂ 403. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂ 404. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ (CH₃)₂CH 405. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ (CH₃)₃C 406. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂CH₂ 407. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ (CH₃)₂CHCH₂ 408. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃OCH₂ 409. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃

410. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃SCH₂ 411. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃

412. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ FCH₂ 413. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ F₃C 414. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ C₆H₅ 415. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ C₆H₅CH₂ 416. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂(CH₃)₂C 417. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH2═CH 418. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂OCH₂ 419. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂SCH₂ 420. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃

421. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃

422. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CF₃CH₂SCH₂ 423. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ ClCH₂CH₂ 424. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ ClCH₂CH₂CH₂ 425. (CH₃)₃C CH₃ CH3CH2 CH₃ CH₃ NCCH2 426. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃ 427. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂ 428. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂ 429. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ (CH₃)₂CH 430. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ (CH₃)₃C 431. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂CH₂ 432. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ (CH₃)₂CHCH₂ 433. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃OCH₂ 434. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃

435. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃SCH₂ 436. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃

437. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ FCH₂ 438. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ F₃C 439. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ C₆H₅ 440. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ C₆H₅CH₂ 441. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂(CH₃)₂C 442. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH2═CH 443. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂OCH₂ 444. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂SCH₂ 445. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃

446. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃

447. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CF₃CH₂SCH₂ 448. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ ClCH₂CH₂ 449. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ ClCH₂CH₂CH₂ 450. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ NCCH2 451. (CH₃)₃C H CH₃ CH₃ H OCH₃ 452. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₃ 453. (CH₃)₃C H CH₃ CH₃ H O(CH₂)₂CH₃ 454. (CH₃)₃C H CH₃ CH₃ H OCH(CH₃)₂ 455. (CH₃)₃C H CH₃ CH₃ H O(CH₃)₃ 456. (CH₃)₃C H CH₃ CH₃ H O(CH₂)₃CH₃ 457. (CH₃)₃C H CH₃ CH₃ H OCH₂CH(CH₃)₂ 458. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂CH(CH₃)₂ 459. (CH₃)₃C H CH₃ CH₃ H OC(CH₃)₂CH₂CH₃ 460. (CH₃)₃C H CH₃ CH₃ H O(CH₂)₄CH₃ 461. (CH₃)₃C H CH₃ CH₃ H OCH₂Cl 462. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂Cl 463. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂CH₂CH₂Cl 464. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂Cl₂ 465. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂F 466. (CH₃)₃C H CH₃ CH₃ H OCH₂CHF₂ 467. (CH₃)₃C H CH₃ CH₃ H OCH₂CF₃ 468. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂OCH₃ 469. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂OCH₂CH₃ 470. (CH₃)₃C H CH₃ CH₃ H OCH₂OCH₂CH₃ 471. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂SCH₃ 472. (CH₃)₃C H CH₃ CH₃ H OCH₂C₅H₆ 473. (CH₃)₃C H CH₃ CH₃ H OCH₂(4-Cl₅H₆) 474. (CH₃)₃C H CH₃ CH₃ H OCH₂C═CH₂ 475. (CH₃)₃C H CH₃ CH₃ H OCH₂(C═CH)CH₃ 476. (CH₃)₃C H CH₃ CH₃ H OCH₂C≡CH 477. (CH₃)₃C H CH₃ CH₃ H OCH₂COOCH₃ 478. (CH₃)₃C H CH₃ CH₃ H OCH₂COOCH₂CH₃ 479. (CH₃)₃C H CH₃ CH₃ H SCH₃ 480. (CH₃)₃C H CH₃ CH₃ H SCH₂CH₃ 481. (CH₃)₃C H CH₃ CH₃ H SCH2COOCH3 482. (CH₃)₃C H CH₃ CH₃ H SCH2(4-ClC5H6) 483. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₃ 484. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₃ 485. (CH₃)₃C CH₃ CH₃ CH₃ H O(CH₂)₂CH₃ 486. (CH₃)₃C CH₃ CH₃ CH₃ H OCH(CH₃)₂ 487. (CH₃)₃C CH₃ CH₃ CH₃ H O(CH₃)₃ 488. (CH₃)₃C CH₃ CH₃ CH₃ H O(CH₂)₃CH₃ 489. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH(CH₃)₂ 490. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂CH(CH₃)₂ 491. (CH₃)₃C CH₃ CH₃ CH₃ H OC(CH₃)₂CH₂CH₃ 492. (CH₃)₃C CH₃ CH₃ CH₃ H O(CH₂)₄CH₃ 493. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂Cl 494. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂Cl 495. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂CH₂CH₂Cl 496. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂Cl₂ 497. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂F 498. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CHF₂ 499. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CF₃ 500. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂OCH₃ 501. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂OCH₂CH₃ 502. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂OCH₂CH₃ 503. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂SCH₃ 504. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂C₅H₆ 505. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂(4-ClC₅H₆) 506. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂C═CH₂ 507. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂(C═CH)CH₃ 508. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂C≡CH 509. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂COOCH₃ 510. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂COOCH₂CH₃ 511. (CH₃)₃C CH₃ CH₃ CH₃ H SCH₃ 512. (CH₃)₃C CH₃ CH₃ CH₃ H SCH₂CH₃ 513. (CH₃)₃C CH₃ CH₃ CH₃ H SCH2COOCH3 514. (CH₃)₃C CH₃ CH₃ CH₃ H SCH2(4-ClC5H6) 515. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₃ 516. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₃ 517. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H O(CH₂)₂CH₃ 518. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH(CH₃)₂ 519. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H O(CH₃)₃ 520. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H O(CH₂)₃CH₃ 521. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH(CH₃)₂ 522. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂CH(CH₃)₂ 523. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OC(CH₃)₂CH₂CH₃ 524. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H O(CH₂)₄CH₃ 525. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂Cl 526. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂Cl 527. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂CH₂CH₂Cl 528. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂Cl₂ 529. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂F 530. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CHF₂ 531. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CF₃ 532. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂OCH₃ 533. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂OCH₂CH₃ 534. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂OCH₂CH₃ 535. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂SCH₃ 536. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂C₅H₆ 537. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂(4-ClC₅H₆) 538. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂C═CH₂ 539. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂(C═CH)CH₃ 540. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂C≡CH 541. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂COOCH₃ 542. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂COOCH₂CH₃ 543. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H SCH₃ 544. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H SCH₂CH₃ 545. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H SCH2COOCH3 546. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H SCH2(4-ClC5H6) 547. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₃ 548. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₃ 549. (CH₃)₃C H CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 550. (CH₃)₃C H CH₃CH₂ CH₃ H OCH(CH₃)₂ 551. (CH₃)₃C H CH₃CH₂ CH₃ H O(CH₃)₃ 552. (CH₃)₃C H CH₃CH₂ CH₃ H O(CH₂)₃CH₃ 553. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH(CH₃)₂ 554. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂CH(CH₃)₂ 555. (CH₃)₃C H CH₃CH₂ CH₃ H OC(CH₃)₂CH₂CH₃ 556. (CH₃)₃C H CH₃CH₂ CH₃ H O(CH₂)₄CH₃ 557. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂Cl 558. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂Cl 559. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂CH₂CH₂Cl 560. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂Cl₂ 561. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂F 562. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CHF₂ 563. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CF₃ 564. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂OCH₃ 565. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂OCH₂CH₃ 566. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂OCH₂CH₃ 567. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂SCH₃ 568. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂C₅H₆ 569. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂(4-ClC₅H₆) 570. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂C═CH₂ 571. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂(C═CH)CH₃ 572. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂C≡CH 573. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂COOCH₃ 574. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂COOCH₂CH₃ 575. (CH₃)₃C H CH₃CH₂ CH₃ H SCH₃ 576. (CH₃)₃C H CH₃CH₂ CH₃ H SCH₂CH₃ 577. (CH₃)₃C H CH₃CH₂ CH₃ H SCH2COOCH3 578. (CH₃)₃C H CH₃CH₂ CH₃ H SCH2(4-ClC5H6) 579. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₃ 580. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₃ 581. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 582. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH(CH₃)₂ 583. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H O(CH₃)₃ 584. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H O(CH₂)₃CH₃ 585. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH(CH₃)₂ 586. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂CH(CH₃)₂ 587. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OC(CH₃)₂CH₂CH₃ 588. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H O(CH₂)₄CH₃ 589. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂Cl 590. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂Cl 591. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂CH₂CH₂Cl 592. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂Cl₂ 593. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂F 594. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CHF₂ 595. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CF₃ 596. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂OCH₃ 597. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂OCH₂CH₃ 598. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂OCH₂CH₃ 599. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂SCH₃ 600. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂C₅H₆ 601. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂(4-ClC₅H₆) 602. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂C═CH₂ 603. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂(C═CH)CH₃ 604. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂C≡CH 605. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂COOCH₃ 606. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂COOCH₂CH₃ 607. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H SCH₃ 608. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H SCH₂CH₃ 609. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H SCH2COOCH3 610. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H SCH2(4-ClC5H6) 611. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₃ 612. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₃ 613. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 614. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH(CH₃)₂ 615. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H O(CH₃)₃ 616. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 617. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH(CH₃)₂ 618. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂CH(CH₃)₂ 619. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OC(CH₃)₂CH₂CH₃ 620. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H O(CH₂)₄CH₃ 621. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂Cl 622. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂Cl 623. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂CH₂CH₂Cl 624. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂Cl₂ 625. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂F 626. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CHF₂ 627. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CF₃ 628. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂OCH₃ 629. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂OCH₂CH₃ 630. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂OCH₂CH₃ 631. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂SCH₃ 632. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂C₅H₆ 633. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂(4-ClC₅H₆) 634. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂C═CH₂ 635. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂(C═CH)CH₃ 636. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂C≡CH 637. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂COOCH₃ 638. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂COOCH₂CH₃ 639. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H SCH₃ 640. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H SCH₂CH₃ 641. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H SCH2COOCH3 642. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H SCH2(4-ClC5H6) 643. (CH₃)₃C H CH₃ CH₃ Cl OCH₃ 644. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₃ 645. (CH₃)₃C H CH₃ CH₃ Cl O(CH₂)₂CH₃ 646. (CH₃)₃C H CH₃ CH₃ Cl OCH(CH₃)₂ 647. (CH₃)₃C H CH₃ CH₃ Cl O(CH₃)₃ 648. (CH₃)₃C H CH₃ CH₃ Cl O(CH₂)₃CH₃ 649. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH(CH₃)₂ 650. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 651. (CH₃)₃C H CH₃ CH₃ Cl OC(CH₃)₂CH₂CH₃ 652. (CH₃)₃C H CH₃ CH₃ Cl O(CH₂)₄CH₃ 653. (CH₃)₃C H CH₃ CH₃ Cl OCH₂Cl 654. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂Cl 655. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 656. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂Cl₂ 657. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂F 658. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CHF₂ 659. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CF₃ 660. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂OCH₃ 661. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂OCH₂CH₃ 662. (CH₃)₃C H CH₃ CH₃ Cl OCH₂OCH₂CH₃ 663. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂SCH₃ 664. (CH₃)₃C H CH₃ CH₃ Cl OCH₂C₅H₆ 665. (CH₃)₃C H CH₃ CH₃ Cl OCH₂(4-ClC₅H₆) 666. (CH₃)₃C H CH₃ CH₃ Cl OCH₂C═CH₂ 667. (CH₃)₃C H CH₃ CH₃ Cl OCH₂(C═CH)CH₃ 668. (CH₃)₃C H CH₃ CH₃ Cl OCH₂C≡CH 669. (CH₃)₃C H CH₃ CH₃ Cl OCH₂COOCH₃ 670. (CH₃)₃C H CH₃ CH₃ Cl OCH₂COOCH₂CH₃ 671. (CH₃)₃C H CH₃ CH₃ Cl SCH₃ 672. (CH₃)₃C H CH₃ CH₃ Cl SCH₂CH₃ 673. (CH₃)₃C H CH₃ CH₃ Cl SCH2COOCH3 674. (CH₃)₃C H CH₃ CH₃ Cl SCH2(4-ClC5H6) 675. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₃ 676. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₃ 677. (CH₃)₃C CH₃ CH₃ CH₃ Cl O(CH₂)₂CH₃ 678. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH(CH₃)₂ 679. (CH₃)₃C CH₃ CH₃ CH₃ Cl O(CH₃)₃ 680. (CH₃)₃C CH₃ CH₃ CH₃ Cl O(CH₂)₃CH₃ 681. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH(CH₃)₂ 682. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 683. (CH₃)₃C CH₃ CH₃ CH₃ Cl OC(CH₃)₂CH₂CH₃ 684. (CH₃)₃C CH₃ CH₃ CH₃ Cl O(CH₂)₄CH₃ 685. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂Cl 686. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂Cl 687. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 688. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂Cl₂ 689. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂F 690. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CHF₂ 691. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CF₃ 692. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂OCH₃ 693. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂OCH₂CH₃ 694. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂OCH₂CH₃ 695. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂SCH₃ 696. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂C₅H₆ 697. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂(4-ClC₅H₆) 698. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂C═CH₂ 699. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂(C═CH)CH₃ 700. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂C≡CH 701. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂COOCH₃ 702. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂COOCH₂CH₃ 703. (CH₃)₃C CH₃ CH₃ CH₃ Cl SCH₃ 704. (CH₃)₃C CH₃ CH₃ CH₃ Cl SCH₂CH₃ 705. (CH₃)₃C CH₃ CH₃ CH₃ Cl SCH2COOCH3 706. (CH₃)₃C CH₃ CH₃ CH₃ Cl SCH2(4-ClC5H6) 707. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₃ 708. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₃ 709. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl O(CH₂)₂CH₃ 710. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH(CH₃)₂ 711. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl O(CH₃)₃ 712. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl O(CH₂)₂CH₃ 713. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH(CH₃)₂ 714. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 715. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OC(CH₃)₂CH₂CH₃ 716. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl O(CH₂)₄CH₃ 717. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂Cl 718. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂Cl 719. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 720. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂Cl₂ 721. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂F 722. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CHF₂ 723. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CF₃ 724. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂OCH₃ 725. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂OCH₂CH₃ 726. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂OCH₂CH₃ 727. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂SCH₃ 728. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂C₅H₆ 729. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂(4-ClC₅H₆) 730. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂C═CH₂ 731. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂(C═CH)CH₃ 732. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂C≡CH 733. (CH₃)₃C CH₃CH₂₃ CH₃ CH₃ Cl OCH₂COOCH₃ 734. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂COOCH₂CH₃ 735. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl SCH₃ 736. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl SCH₂CH₃ 737. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl SCH2COOCH3 738. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl SCH2(4-ClC5H6) 739. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₃ 740. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₃ 741. (CH₃)₃C H CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 742. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH(CH₃)₂ 743. (CH₃)₃C H CH₃CH₂ CH₃ Cl O(CH₃)₃ 744. (CH₃)₃C H CH₃CH₂ CH₃ Cl O(CH₂)₃CH₃ 745. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH(CH₃)₂ 746. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 747. (CH₃)₃C H CH₃CH₂ CH₃ Cl OC(CH₃)₂CH₂CH₃ 748. (CH₃)₃C H CH₃CH₂ CH₃ Cl O(CH₂)₄CH₃ 749. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂Cl 750. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂Cl 751. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 752. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂Cl₂ 753. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂F 754. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CHF₂ 755. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CF₃ 756. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₃ 757. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₂CH₃ 758. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂OCH₂CH₃ 759. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂SCH₃ 760. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂C₅H₆ 761. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂(4-ClC₅H₆) 762. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂C═CH₂ 763. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂(C═CH)CH₃ 764. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂C≡CH 765. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂COOCH₃ 766. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂COOCH₂CH₃ 767. (CH₃)₃C H CH₃CH₂ CH₃ Cl SCH₃ 768. (CH₃)₃C H CH₃CH₂ CH₃ Cl SCH₂CH₃ 769. (CH₃)₃C H CH₃CH₂ CH₃ Cl SCH2COOCH3 770. (CH₃)₃C H CH₃CH₂ CH₃ Cl SCH2(4-ClC5H6) 771. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₃ 772. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₃ 773. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 774. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH(CH₃)₂ 775. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl O(CH₃)₃ 776. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl O(CH₂)₃CH₃ 777. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH(CH₃)₂ 778. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 779. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OC(CH₃)₂CH₂CH₃ 780. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl O(CH₂)₄CH₃ 781. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂Cl 782. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂Cl 783. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 784. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂Cl₂ 785. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂F 786. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CHF₂ 787. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CF₃ 788. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₃ 789. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₂CH₃ 790. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂OCH₂CH₃ 791. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂SCH₃ 792. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂C₅H₆ 793. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂(4-ClC₅H₆) 794. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂C═CH₂ 795. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂(C═CH)CH₃ 796. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂C≡CH 797. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂COOCH₃ 798. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂COOCH₂CH₃ 799. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl SCH₃ 800. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl SCH₂CH₃ 801. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl SCH2COOCH3 802. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl SCH2(4-ClC5H6) 803. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₃ 804. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₃ 805. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 806. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH(CH₃)₂ 807. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl O(CH₃)₃ 808. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 809. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH(CH₃)₂ 810. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 811. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OC(CH₃)₂CH₂CH₃ 812. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl O(CH₂)₄CH₃ 813. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂Cl 814. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂Cl 815. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 816. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂Cl₂ 817. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂F 818. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CHF₂ 819. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CF₃ 820. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₃ 821. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₂CH₃ 822. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂OCH₂CH₃ 823. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂SCH₃ 824. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂C₅H₆ 825. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂(4-ClC₅H₆) 826. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂C═CH₂ 827. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂(C═CH)CH₃ 828. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂C≡CH 829. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂COOCH₃ 830. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂COOCH₂CH₃ 831. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl SCH₃ 832. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl SCH₂CH₃ 833. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl SCH2COOCH3 834. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl SCH2(4-ClC5H6) 835. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₃ 836. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₃ 837. (CH₃)₃C H CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 838. (CH₃)₃C H CH₃ CH₃ CH₃ OCH(CH₃)₂ 839. (CH₃)₃C H CH₃ CH₃ CH₃ O(CH₃)₃ 840. (CH₃)₃C H CH₃ CH₃ CH₃ O(CH₂)₃CH₃ 841. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH(CH₃)₂ 842. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 843. (CH₃)₃C H CH₃ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 844. (CH₃)₃C H CH₃ CH₃ CH₃ O(CH₂)₄CH₃ 845. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂Cl 846. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂Cl 847. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 848. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂Cl₂ 849. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂F 850. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CHF₂ 851. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CF₃ 852. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂OCH₃ 853. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 854. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂OCH₂CH₃ 855. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂SCH₃ 856. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂C₅H₆ 857. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂(4-ClC₅H₆) 858. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂C═CH₂ 859. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂(C═CH)CH₃ 860. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂C≡CH 861. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂COOCH₃ 862. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂COOCH₂CH₃ 863. (CH₃)₃C H CH₃ CH₃ CH₃ SCH₃ 864. (CH₃)₃C H CH₃ CH₃ CH₃ SCH₂CH₃ 865. (CH₃)₃C H CH₃ CH₃ CH₃ SCH2COOCH3 866. (CH₃)₃C H CH₃ CH₃ CH₃ SCH2(4-ClC5H6) 867. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₃ 868. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₃ 869. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 870. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH(CH₃)₂ 871. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ O(CH₃)₃ 872. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ O(CH₂)₃CH₃ 873. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH(CH₃)₂ 874. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 875. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 876. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ O(CH₂)₄CH₃ 877. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂Cl 878. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂Cl 879. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 880. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂Cl₂ 881. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂F 882. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CHF₂ 883. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CF₃ 884. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂OCH₃ 885. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 886. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂OCH₂CH₃ 887. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂SCH₃ 888. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂C₅H₆ 889. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂(4-ClC₅H₆) 890. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂C═CH₂ 891. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂(C═CH)CH₃ 892. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂C≡CH 893. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂COOCH₃ 894. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂COOCH₂CH₃ 895. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ SCH₃ 896. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ SCH₂CH₃ 897. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ SCH2COOCH3 898. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ SCH2(4-ClC5H6) 899. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₃ 900. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₃ 901. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 902. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH(CH₃)₂ 903. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ O(CH₃)₃ 904. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 905. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH(CH₃)₂ 906. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 907. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 908. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ O(CH₂)₄CH₃ 909. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂Cl 910. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂Cl 911. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 912. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂Cl₂ 913. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂F 914. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CHF₂ 915. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CF₃ 916. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂OCH₃ 917. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 918. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂OCH₂CH₃ 919. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂SCH₃ 920. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂C₅H₆ 921. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂(4-ClC₅H₆) 922. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂C═CH₂ 923. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂(C═CH)CH₃ 924. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂C≡CH 925. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂COOCH₃ 926. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂COOCH₂CH₃ 927. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ SCH₃ 928. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ SCH₂CH₃ 929. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ SCH2COOCH3 930. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ SCH2(4-ClC5H6) 931. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₃ 932. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₃ 933. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 934. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH(CH₃)₂ 935. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ O(CH₃)₃ 936. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ O(CH₂)₃CH₃ 937. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH(CH₃)₂ 938. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 939. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 940. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ O(CH₂)₄CH₃ 941. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂Cl 942. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl 943. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 944. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl₂ 945. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂F 946. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CHF₂ 947. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CF₃ 948. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₃ 949. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 950. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂OCH₂CH₃ 951. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂SCH₃ 952. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂C₅H₆ 953. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂(4-ClC₅H₆) 954. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂C═CH₂ 955. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂(C═CH)CH₃ 956. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂C≡CH 957. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂COOCH₃ 958. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂COOCH₂CH₃ 959. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ SCH₃ 960. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ SCH₂CH₃ 961. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ SCH2COOCH3 962. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ SCH2(4-ClC5H6) 963. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₃ 964. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₃ 965. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 966. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH(CH₃)₂ 967. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ O(CH₃)₃ 968. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ O(CH₂)₃CH₃ 969. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH(CH₃)₂ 970. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 971. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 972. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ O(CH₂)₄CH₃ 973. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂Cl 974. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl 975. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 976. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl₂ 977. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂F 978. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CHF₂ 979. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CF₃ 980. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₃ 981. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 982. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂OCH₂CH₃ 983. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂SCH₃ 984. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂C₅H₆ 985. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂(4-ClC₅H₆) 986. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂C═CH₂ 987. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂(C═CH)CH₃ 988. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂C≡CH 989. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂COOCH₃ 990. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂COOCH₂CH₃ 991. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ SCH₃ 992. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ SCH₂CH₃ 993. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ SCH2COOCH3 994. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ SCH2(4-ClC5H6) 995. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₃ 996. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₃ 997. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 998. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH(CH₃)₂ 999. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ O(CH₃)₃ 1000. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 1001. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH(CH₃)₂ 1002. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 1003. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 1004. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ O(CH₂)₄CH₃ 1005. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂Cl 1006. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl 1007. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 1008. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl₂ 1009. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂F 1010. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CHF₂ 1011. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CF₃ 1012. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₃ 1013. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 1014. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂OCH₂CH₃ 1015. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂SCH₃ 1016. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂C₅H₆ 1017. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂(4-ClC₅H₆) 1018. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂C═CH₂ 1019. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂(C═CH)CH₃ 1020. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂C≡CH 1021. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂COOCH₃ 1022. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂COOCH₂CH₃ 1023. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ SCH₃ 1024. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ SCH₂CH₃ 1025. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ SCH2COOCH3 1026. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ SCH2(4-ClC5H6) 1027. (CH₃)₃C CH₃ CH₃CH₂ CH(CH₃)2 H OCH₂CH₃ 1028. (CH₃)₃C CH₃ CH₃CH₂ CH(CH₃)2 H OCH₃ 1029. (CH₃)₃C CH₃ CH₃CH₂ CH(CH₃)2 H O(CH₂)₃CH₃ 1030. (CH₃)₃C CH₃ CH₃CH₂ CH(CH₃)2 H OCH₂CH(CH₃)₂ 1031. (CH₃)₃C CH₃ CH₃CH₂ CH(CH₃)2 H OCH₂CH₂OCH₃ 1032. (CH₃)₃C CH₃ CH₃CH₂ CH(CH₃)2 H OCH₂CH₂CH(CH₃)₂ 1033. (CH₃)₃C CH₃ CH₃CH₂ CH(CH₃)2 H OCH₂C═CH₂ 1034. (CH₃)₃C CH₃ CH₃CH₂ CH(CH₃)2 H OCH₂C≡CH 1035. (CH₃)₃C CH₃ CH₃CH₂ CH(CH₃)2 H CH₃ 1036. (CH₃)₃C CH₃ CH₃ CH₃ Br OCH₃ 1037. (CH₃)₃C CH₃ CH₃ CH₃ Br OCH₂CH₃ 1038. (CH₃)₃C CH₃ CH₃ CH₃ Br OCH₂CF₃ 1039. (CH₃)₃C CH₃ CH₃ CH₃ Br O(CH₂)₃CH₃ 1040. (CH₃)₃C CH₃ CH₃ CH₃ Br OCH₂CH(CH₃)₂ 1041. (CH₃)₃C CH₃ CH₃ CH₃ Br OCH₂CH(CH₃)₂ 1042. (CH₃)₃C CH₃ CH₃ CH₃ Br OCH₂C═CH₂ 1043. (CH₃)₃C CH₃ CH₃ CH₃ Br OCH₂CH₂OCH₃ 1044. (CH₃)₃C CH₃ CH₃ CH₃ Br CH₃ 1045. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₃ 1046. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂CH₃ 1047. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂CF₃ 1048. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl O(CH₂)₃CH₃ 1049. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl O(CH₂)₃CH₃ 1050. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂CH(CH₃)₂ 1051. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂C═CH₂ 1052. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂CH₂OCH₃ 1053. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂C≡CH 1054. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl CH₃ 1055. (CH₃)₃C CH₃ CH₂CH₃ CH₃ Br OCH₃ 1056. (CH₃)₃C CH₃ CH₂CH₃ CH₃ Br OCH₂CH₃ 1057. (CH₃)₃C CH₃ CH₂CH₃ CH₃ Br OCH₂CF₃ 1058. (CH₃)₃C CH₃ CH₂CH₃ CH₃ Br O(CH₂)₃CH₃ 1059. (CH₃)₃C CH₃ CH₂CH₃ CH₃ Br O(CH₂)₃CH₃ 1060. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂CF₃ 1061. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl O(CH₂)₃CH₃ 1062. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl O(CH₂)₃CH₃ 1063. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂CH(CH₃)₂ 1064. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂C═CH₂ 1065. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂CH₂OCH₃ 1066. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl OCH₂C≡CH 1067. (CH₃)₃C CH₃ CH₃ CH₂CH₃ Cl CH₃

For pyrazole derivatives represented by the formula stru-1 provided herein, when substituents R1, R2, R4, and R5 are hydrogen and Q is oxygen, as an example, when the pyrazole derivative represented by the formula stru-1 is a Z-type compound, the pyrazole derivative represented by the formula stru-1 may be a compound shown in Table 2.

TABLE 2 No. R3 R9 R8 R6 R7 L-R10 1068. (CH₃)₃C H CH₃ CH₃ H CH₃ 1069. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂ 1070. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂CH₂ 1071. (CH₃)₃C H CH₃ CH₃ H (CH₃)₂CH 1072. (CH₃)₃C H CH₃ CH₃ H (CH₃)₃C 1073. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂CH₂CH₂ 1074. (CH₃)₃C H CH₃ CH₃ H (CH₃)₂CHCH₂ 1075. (CH₃)₃C H CH₃ CH₃ H CH₃OCH₂ 1076. (CH₃)₃C H CH₃ CH₃ H

1077. (CH₃)₃C H CH₃ CH₃ H CH₃SCH₂ 1078. (CH₃)₃C H CH₃ CH₃ H

1079. (CH₃)₃C H CH₃ CH₃ H FCH₂ 1080. (CH₃)₃C H CH₃ CH₃ H F₃C 1081. (CH₃)₃C H CH₃ CH₃ H C₆H₅ 1082. (CH₃)₃C H CH₃ CH₃ H C₆H₅CH₂ 1083. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂(CH₃)₂C 1084. (CH₃)₃C H CH₃ CH₃ H CH2═CH 1085. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂OCH₂ 1086. (CH₃)₃C H CH₃ CH₃ H CH₃CH₂SCH₂ 1087. (CH₃)₃C H CH₃ CH₃ H

1088. (CH₃)₃C H CH₃ CH₃ H

1089. (CH₃)₃C H CH₃ CH₃ H CF₃CH₂SCH₂ 1090. (CH₃)₃C H CH₃ CH₃ H ClCH₂CH₂ 1091. (CH₃)₃C H CH₃ CH₃ H ClCH₂CH₂CH₂ 1092. (CH₃)₃C H CH₃ CH₃ H NCCH2 1093. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃ 1094. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂ 1095. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂CH₂ 1096. (CH₃)₃C CH₃ CH₃ CH₃ H (CH₃)₂CH 1097. (CH₃)₃C CH₃ CH₃ CH₃ H (CH₃)₃C 1098. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂CH₂CH₂ 1099. (CH₃)₃C CH₃ CH₃ CH₃ H (CH₃)₂CHCH₂ 1100. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃OCH₂ 1101. (CH₃)₃C CH₃ CH₃ CH₃ H

1102. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃SCH₂ 1103. (CH₃)₃C CH₃ CH₃ CH₃ H

1104. (CH₃)₃C CH₃ CH₃ CH₃ H FCH₂ 1105. (CH₃)₃C CH₃ CH₃ CH₃ H F₃C 1106. (CH₃)₃C CH₃ CH₃ CH₃ H C₆H₅ 1107. (CH₃)₃C CH₃ CH₃ CH₃ H C₆H₅CH₂ 1108. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂(CH₃)₂C 1109. (CH₃)₃C CH₃ CH₃ CH₃ H CH2═CH 1110. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂OCH₂ 1111. (CH₃)₃C CH₃ CH₃ CH₃ H CH₃CH₂SCH₂ 1112. (CH₃)₃C CH₃ CH₃ CH₃ H

1113. (CH₃)₃C CH₃ CH₃ CH₃ H

1114. (CH₃)₃C CH₃ CH₃ CH₃ H CF₃CH₂SCH₂ 1115. (CH₃)₃C CH₃ CH₃ CH₃ H ClCH₂CH₂ 1116. (CH₃)₃C CH₃ CH₃ CH₃ H ClCH₂CH₂CH₂ 1117. (CH₃)₃C CH3 CH₃ CH₃ H NCCH2 1118. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃ 1119. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂ 1120. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂CH₂ 1121. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H (CH₃)₂CH 1122. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H (CH₃)₃C 1123. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂CH₂CH₂ 1124. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H (CH₃)₂CHCH₂ 1125. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃OCH₂ 1126. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H

1127. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃SCH₂ 1128. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H

1129. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H FCH₂ 1130. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H F₃C 1131. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H C₆H₅ 1132. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H C₆H₅CH₂ 1133. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂(CH₃)₂C 1134. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH2═CH 1135. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂OCH₂ 1136. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CH₃CH₂SCH₂ 1137. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H

1138. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H

1139. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CF₃CH₂SCH₂ 1140. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H ClCH₂CH₂ 1141. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H ClCH₂CH₂CH₂ 1142. (CH₃)₃C CH3CH2 CH₃ CH₃ H NCCH2 1143. (CH₃)₃C H CH₃ CH₃ Cl CH₃ 1144. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂ 1145. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂CH₂ 1146. (CH₃)₃C H CH₃ CH₃ Cl (CH₃)₂CH 1147. (CH₃)₃C H CH₃ CH₃ Cl (CH₃)₃C 1148. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂CH₂CH₂ 1149. (CH₃)₃C H CH₃ CH₃ Cl (CH₃)₂CHCH₂ 1150. (CH₃)₃C H CH₃ CH₃ Cl CH₃OCH₂ 1151. (CH₃)₃C H CH₃ CH₃ Cl

1152. (CH₃)₃C H CH₃ CH₃ Cl CH₃SCH₂ 1153. (CH₃)₃C H CH₃ CH₃ Cl

1154. (CH₃)₃C H CH₃ CH₃ Cl FCH₂ 1155. (CH₃)₃C H CH₃ CH₃ Cl F₃C 1156. (CH₃)₃C H CH₃ CH₃ Cl C₆H₅ 1157. (CH₃)₃C H CH₃ CH₃ Cl C₆H₅CH₂ 1158. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂(CH₃)₂C 1159. (CH₃)₃C H CH₃ CH₃ Cl CH2═CH 1160. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂OCH₂ 1161. (CH₃)₃C H CH₃ CH₃ Cl CH₃CH₂SCH₂ 1162. (CH₃)₃C H CH₃ CH₃ Cl

1163. (CH₃)₃C H CH₃ CH₃ Cl

1164. (CH₃)₃C H CH₃ CH₃ Cl CF₃CH₂SCH₂ 1165. (CH₃)₃C H CH₃ CH₃ Cl ClCH₂CH₂ 1166. (CH₃)₃C H CH₃ CH₃ Cl ClCH₂CH₂CH₂ 1167. (CH₃)₃C H CH₃ CH₃ Cl NCCH2 1168. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃ 1169. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂ 1170. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂CH₂ 1171. (CH₃)₃C CH₃ CH₃ CH₃ Cl (CH₃)₂CH 1172. (CH₃)₃C CH₃ CH₃ CH₃ Cl (CH₃)₃C 1173. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂CH₂CH₂ 1174. (CH₃)₃C CH₃ CH₃ CH₃ Cl (CH₃)₂CHCH₂ 1175. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃OCH₂ 1176. (CH₃)₃C CH₃ CH₃ CH₃ Cl

1177. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃SCH₂ 1178. (CH₃)₃C CH₃ CH₃ CH₃ Cl

1179. (CH₃)₃C CH₃ CH₃ CH₃ Cl FCH₂ 1180. (CH₃)₃C CH₃ CH₃ CH₃ Cl F₃C 1181. (CH₃)₃C CH₃ CH₃ CH₃ Cl C₆H₅ 1182. (CH₃)₃C CH₃ CH₃ CH₃ Cl C₆H₅CH₂ 1183. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂(CH₃)₂C 1184. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH2═CH 1185. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂OCH₂ 1186. (CH₃)₃C CH₃ CH₃ CH₃ Cl CH₃CH₂SCH₂ 1187. (CH₃)₃C CH₃ CH₃ CH₃ Cl

1188. (CH₃)₃C CH₃ CH₃ CH₃ Cl

1189. (CH₃)₃C CH₃ CH₃ CH₃ Cl CF₃CH₂SCH₂ 1190. (CH₃)₃C CH₃ CH₃ CH₃ Cl ClCH₂CH₂ 1191. (CH₃)₃C CH₃ CH₃ CH₃ Cl ClCH₂CH₂CH₂ 1192. (CH₃)₃C CH3 CH₃ CH₃ Cl NCCH2 1193. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃ 1194. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂ 1195. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂CH₂ 1196. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl (CH₃)₂CH 1197. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl (CH₃)₃C 1198. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂CH₂CH₂ 1199. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl (CH₃)₂CHCH₂ 1200. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃OCH₂ 1201. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl

1202. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃SCH₂ 1203. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl

1204. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl FCH₂ 1205. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl F₃C 1206. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl C₆H₅ 1207. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl C₆H₅CH₂ 1208. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂(CH₃)₂C 1209. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH2═CH 1210. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂OCH₂ 1211. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CH₃CH₂SCH₂ 1212. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl

1213. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl

1214. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl CF₃CH₂SCH₂ 1215. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl ClCH₂CH₂ 1216. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl ClCH₂CH₂CH₂ 1217. (CH₃)₃C CH3CH2 CH₃ CH₃ Cl NCCH2 1218. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃ 1219. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂ 1220. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂CH₂ 1221. (CH₃)₃C H CH₃ CH₃ CH₃ (CH₃)₂CH 1222. (CH₃)₃C H CH₃ CH₃ CH₃ (CH₃)₃C 1223. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂CH₂CH₂ 1224. (CH₃)₃C H CH₃ CH₃ CH₃ (CH₃)₂CHCH₂ 1225. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃OCH₂ 1226. (CH₃)₃C H CH₃ CH₃ CH₃

1227. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃SCH₂ 1228. (CH₃)₃C H CH₃ CH₃ CH₃

1229. (CH₃)₃C H CH₃ CH₃ CH₃ FCH₂ 1230. (CH₃)₃C H CH₃ CH₃ CH₃ F₃C 1231. (CH₃)₃C H CH₃ CH₃ CH₃ C₆H₅ 1232. (CH₃)₃C H CH₃ CH₃ CH₃ C₆H₅CH₂ 1233. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂(CH₃)₂C 1234. (CH₃)₃C H CH₃ CH₃ CH₃ CH2═CH 1235. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂OCH₂ 1236. (CH₃)₃C H CH₃ CH₃ CH₃ CH₃CH₂SCH₂ 1237. (CH₃)₃C H CH₃ CH₃ CH₃

1238. (CH₃)₃C H CH₃ CH₃ CH₃

1239. (CH₃)₃C H CH₃ CH₃ CH₃ CF₃CH₂SCH₂ 1240. (CH₃)₃C H CH₃ CH₃ CH₃ ClCH₂CH₂ 1241. (CH₃)₃C H CH₃ CH₃ CH₃ ClCH₂CH₂CH₂ 1242. (CH₃)₃C H CH₃ CH₃ CH₃ NCCH2 1243. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃ 1244. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂ 1245. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂CH₂ 1246. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ (CH₃)₂CH 1247. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ (CH₃)₃C 1248. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂CH₂CH₂ 1249. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ (CH₃)₂CHCH₂ 1250. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃OCH₂ 1251. (CH₃)₃C CH₃ CH₃ CH₃ CH₃

1252. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃SCH₂ 1253. (CH₃)₃C CH₃ CH₃ CH₃ CH₃

1254. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ FCH₂ 1255. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ F₃C 1256. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ C₆H₅ 1257. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ C₆H₅CH₂ 1258. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂(CH₃)₂C 1259. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH2═CH 1260. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂OCH₂ 1261. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CH₃CH₂SCH₂ 1262. (CH₃)₃C CH₃ CH₃ CH₃ CH₃

1263. (CH₃)₃C CH₃ CH₃ CH₃ CH₃

1264. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ CF₃CH₂SCH₂ 1265. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ ClCH₂CH₂ 1266. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ ClCH₂CH₂CH₂ 1267. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ NCCH2 1268. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃ 1269. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂ 1270. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂CH₂ 1271. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ (CH₃)₂CH 1272. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ (CH₃)₃C 1273. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂CH₂CH₂ 1274. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ (CH₃)₂CHCH₂ 1275. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃OCH₂ 1276. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃

1277. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃SCH₂ 1278. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃

1279. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ FCH₂ 1280. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ F₃C 1281. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ C₆H₅ 1282. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ C₆H₅CH₂ 1283. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂(CH₃)₂C 1284. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH2═CH 1285. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂OCH₂ 1286. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ CH₃CH₂SCH₂ 1287. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃

1288. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃

1289. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H CF₃CH₂SCH₂ 1290. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H ClCH₂CH₂ 1291. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H ClCH₂CH₂CH₂ 1292. (CH₃)₃C CH3CH2 CH₃ CH₃ H NCCH2 1293. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃ 1294. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂ 1295. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂CH₂ 1296. (CH₃)₃C H CH₃CH₂ CH₃ H (CH₃)₂CH 1297. (CH₃)₃C H CH₃CH₂ CH₃ H (CH₃)₃C 1298. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂CH₂CH₂ 1299. (CH₃)₃C H CH₃CH₂ CH₃ H (CH₃)₂CHCH₂ 1300. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃OCH₂ 1301. (CH₃)₃C H CH₃CH₂ CH₃ H

1302. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃SCH₂ 1303. (CH₃)₃C H CH₃CH₂ CH₃ H

1304. (CH₃)₃C H CH₃CH₂ CH₃ H FCH₂ 1305. (CH₃)₃C H CH₃CH₂ CH₃ H F₃C 1306. (CH₃)₃C H CH₃CH₂ CH₃ H C₆H₅ 1307. (CH₃)₃C H CH₃CH₂ CH₃ H C₆H₅CH₂ 1308. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂(CH₃)₂C 1309. (CH₃)₃C H CH₃CH₂ CH₃ H CH2═CH 1310. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂OCH₂ 1311. (CH₃)₃C H CH₃CH₂ CH₃ H CH₃CH₂SCH₂ 1312. (CH₃)₃C H CH₃CH₂ CH₃ H

1313. (CH₃)₃C H CH₃CH₂ CH₃ H

1314. (CH₃)₃C H CH₃CH₂ CH₃ H CF₃CH₂SCH₂ 1315. (CH₃)₃C H CH₃CH₂ CH₃ H ClCH₂CH₂ 1316. (CH₃)₃C H CH₃CH₂ CH₃ H ClCH₂CH₂CH₂ 1317. (CH₃)₃C H CH₃CH₂ CH₃ H NCCH2 1318. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃ 1319. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂ 1320. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂CH₂ 1321. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H (CH₃)₂CH 1322. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H (CH₃)₃C 1323. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂CH₂CH₂ 1324. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H (CH₃)₂CHCH₂ 1325. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃OCH₂ 1326. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H

1327. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃SCH₂ 1328. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H

1329. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H FCH₂ 1330. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H F₃C 1331. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H C₆H₅ 1332. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H C₆H₅CH₂ 1333. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂(CH₃)₂C 1334. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH2═CH 1335. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂OCH₂ 1336. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CH₃CH₂SCH₂ 1337. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H

1338. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H

1339. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H CF₃CH₂SCH₂ 1340. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H ClCH₂CH₂ 1341. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H ClCH₂CH₂CH₂ 1342. (CH₃)₃C CH3 CH₃CH₂ CH₃ H NCCH2 1343. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃ 1344. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂ 1345. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂CH₂ 1346. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H (CH₃)₂CH 1347. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H (CH₃)₃C 1348. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂CH₂CH₂ 1349. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H (CH₃)₂CHCH₂ 1350. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃OCH₂ 1351. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H

1352. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃SCH₂ 1353. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H

1354. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H FCH₂ 1355. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H F₃C 1356. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H C₆H₅ 1357. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H C₆H₅CH₂ 1358. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂(CH₃)₂C 1359. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH2═CH 1360. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂OCH₂ 1361. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CH₃CH₂SCH₂ 1362. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H

1363. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H

1364. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H CF₃CH₂SCH₂ 1365. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H ClCH₂CH₂ 1366. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H ClCH₂CH₂CH₂ 1367. (CH₃)₃C CH3CH2 CH₃CH₂ CH₃ H NCCH2 1368. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃ 1369. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂ 1370. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂CH₂ 1371. (CH₃)₃C H CH₃CH₂ CH₃ Cl (CH₃)₂CH 1372. (CH₃)₃C H CH₃CH₂ CH₃ Cl (CH₃)₃C 1373. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂CH₂CH₂ 1374. (CH₃)₃C H CH₃CH₂ CH₃ Cl (CH₃)₂CHCH₂ 1375. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃OCH₂ 1376. (CH₃)₃C H CH₃CH₂ CH₃ Cl

1377. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃SCH₂ 1378. (CH₃)₃C H CH₃CH₂ CH₃ Cl

1379. (CH₃)₃C H CH₃CH₂ CH₃ Cl FCH₂ 1380. (CH₃)₃C H CH₃CH₂ CH₃ Cl F₃C 1381. (CH₃)₃C H CH₃CH₂ CH₃ Cl C₆H₅ 1382. (CH₃)₃C H CH₃CH₂ CH₃ Cl C₆H₅CH₂ 1383. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂(CH₃)₂C 1384. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH2═CH 1385. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂OCH₂ 1386. (CH₃)₃C H CH₃CH₂ CH₃ Cl CH₃CH₂SCH₂ 1387. (CH₃)₃C H CH₃CH₂ CH₃ Cl

1388. (CH₃)₃C H CH₃CH₂ CH₃ Cl

1389. (CH₃)₃C H CH₃CH₂ CH₃ Cl CF₃CH₂SCH₂ 1390. (CH₃)₃C H CH₃CH₂ CH₃ Cl ClCH₂CH₂ 1391. (CH₃)₃C H CH₃CH₂ CH₃ Cl ClCH₂CH₂CH₂ 1392. (CH₃)₃C H CH₃CH₂ CH₃ Cl NCCH2 1393. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃ 1394. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂ 1395. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂CH₂ 1396. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl (CH₃)₂CH 1397. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl (CH₃)₃C 1398. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂CH₂CH₂ 1399. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl (CH₃)₂CHCH₂ 1400. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃OCH₂ 1401. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl

1402. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃SCH₂ 1403. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl

1404. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl FCH₂ 1405. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl F₃C 1406. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl C₆H₅ 1407. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl C₆H₅CH₂ 1408. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂(CH₃)₂C 1409. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH2═CH 1410. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂OCH₂ 1411. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CH₃CH₂SCH₂ 1412. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl

1413. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl

1414. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl CF₃CH₂SCH₂ 1415. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl ClCH₂CH₂ 1416. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl ClCH₂CH₂CH₂ 1417. (CH₃)₃C CH3 CH₃CH₂ CH₃ Cl NCCH2 1418. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃ 1419. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂ 1420. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂CH₂ 1421. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl (CH₃)₂CH 1422. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl (CH₃)₃C 1423. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂CH₂CH₂ 1424. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl (CH₃)₂CHCH₂ 1425. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃OCH₂ 1426. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl

1427. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃SCH₂ 1428. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl

1429. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl FCH₂ 1430. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl F₃C 1431. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl C₆H₅ 1432. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl C₆H₅CH₂ 1433. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂(CH₃)₂C 1434. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH2═CH 1435. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂OCH₂ 1436. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CH₃CH₂SCH₂ 1437. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl

1438. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl

1439. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl CF₃CH₂SCH₂ 1440. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl ClCH₂CH₂ 1441. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl ClCH₂CH₂CH₂ 1442. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl NCCH2 1443. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃ 1444. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂ 1445. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂ 1446. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ (CH₃)₂CH 1447. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ (CH₃)₃C 1448. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂CH₂ 1449. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ (CH₃)₂CHCH₂ 1450. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃OCH₂ 1451. (CH₃)₃C H CH₃CH₂ CH₃ CH₃

1452. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃SCH₂ 1453. (CH₃)₃C H CH₃CH₂ CH₃ CH₃

1454. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ FCH₂ 1455. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ F₃C 1456. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ C₆H₅ 1457. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ C₆H₅CH₂ 1458. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂(CH₃)₂C 1459. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH2═CH 1460. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂OCH₂ 1461. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CH₃CH₂SCH₂ 1462. (CH₃)₃C H CH₃CH₂ CH₃ CH₃

1463. (CH₃)₃C H CH₃CH₂ CH₃ CH₃

1464. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ CF₃CH₂SCH₂ 1465. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ ClCH₂CH₂ 1466. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ ClCH₂CH₂CH₂ 1467. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ NCCH2 1468. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃ 1469. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂ 1470. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂ 1471. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ (CH₃)₂CH 1472. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ (CH₃)₃C 1473. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂CH₂ 1474. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ (CH₃)₂CHCH₂ 1475. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃OCH₂ 1476. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃

1477. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃SCH₂ 1478. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃

1479. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ FCH₂ 1480. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ F₃C 1481. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ C₆H₅ 1482. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ C₆H₅CH₂ 1483. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂(CH₃)₂C 1484. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH2═CH 1485. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂OCH₂ 1486. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CH₃CH₂SCH₂ 1487. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃

1488. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃

1489. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ CF₃CH₂SCH₂ 1490. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ ClCH₂CH₂ 1491. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ ClCH₂CH₂CH₂ 1492. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ NCCH2 1493. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃ 1494. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂ 1495. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂ 1496. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ (CH₃)₂CH 1497. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ (CH₃)₃C 1498. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂CH₂CH₂ 1499. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ (CH₃)₂CHCH₂ 1500. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃OCH₂ 1501. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃

1502. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃SCH₂ 1503. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃

1504. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ FCH₂ 1505. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ F₃C 1506. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ C₆H₅ 1507. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ C₆H₅CH₂ 1508. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂(CH₃)₂C 1509. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH2═CH 1510. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂OCH₂ 1511. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CH₃CH₂SCH₂ 1512. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃

1513. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃

1514. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ CF₃CH₂SCH₂ 1515. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ ClCH₂CH₂ 1516. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ ClCH₂CH₂CH₂ 1517. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ NCCH2 1518. 1519. (CH₃)₃C H CH₃ CH₃ H OCH₃ 1520. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₃ 1521. (CH₃)₃C H CH₃ CH₃ H O(CH₂)₂CH₃ 1522. (CH₃)₃C H CH₃ CH₃ H OCH(CH₃)₂ 1523. (CH₃)₃C H CH₃ CH₃ H O(CH₃)₃ 1524. (CH₃)₃C H CH₃ CH₃ H O(CH₂)₂CH₃ 1525. (CH₃)₃C H CH₃ CH₃ H OCH₂CH(CH₃)₂ 1526. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂CH(CH₃)₂ 1527. (CH₃)₃C H CH₃ CH₃ H OC(CH₃)₂CH₂CH₃ 1528. (CH₃)₃C H CH₃ CH₃ H O(CH₂)₄CH₃ 1529. (CH₃)₃C H CH₃ CH₃ H OCH₂Cl 1530. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂Cl 1531. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂CH₂CH₂Cl 1532. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂Cl₂ 1533. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂F 1534. (CH₃)₃C H CH₃ CH₃ H OCH₂CHF₂ 1535. (CH₃)₃C H CH₃ CH₃ H OCH₂CF₃ 1536. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂OCH₃ 1537. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂OCH₂CH₃ 1538. (CH₃)₃C H CH₃ CH₃ H OCH₂OCH₂CH₃ 1539. (CH₃)₃C H CH₃ CH₃ H OCH₂CH₂SCH₃ 1540. (CH₃)₃C H CH₃ CH₃ H OCH₂C₅H₆ 1541. (CH₃)₃C H CH₃ CH₃ H OCH₂(4-ClC₅H₆) 1542. (CH₃)₃C H CH₃ CH₃ H OCH₂C═CH₂ 1543. (CH₃)₃C H CH₃ CH₃ H OCH₂(C═CH)CH₃ 1544. (CH₃)₃C H CH₃ CH₃ H OCH₂C≡CH 1545. (CH₃)₃C H CH₃ CH₃ H OCH₂COOCH₃ 1546. (CH₃)₃C H CH₃ CH₃ H OCH₂COOCH₂CH₃ 1547. (CH₃)₃C H CH₃ CH₃ H SCH₃ 1548. (CH₃)₃C H CH₃ CH₃ H SCH₂CH₃ 1549. (CH₃)₃C H CH₃ CH₃ H SCH2COOCH3 1550. (CH₃)₃C H CH₃ CH₃ H SCH2(4-ClC5H6) 1551. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₃ 1552. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₃ 1553. (CH₃)₃C CH₃ CH₃ CH₃ H O(CH₂)₂CH₃ 1554. (CH₃)₃C CH₃ CH₃ CH₃ H OCH(CH₃)₂ 1555. (CH₃)₃C CH₃ CH₃ CH₃ H O(CH₃)₃ 1556. (CH₃)₃C CH₃ CH₃ CH₃ H O(CH₂)₂CH₃ 1557. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH(CH₃)₂ 1558. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂CH(CH₃)₂ 1559. (CH₃)₃C CH₃ CH₃ CH₃ H OC(CH₃)₂CH₂CH₃ 1560. (CH₃)₃C CH₃ CH₃ CH₃ H O(CH₂)₄CH₃ 1561. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂Cl 1562. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂Cl 1563. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂CH₂CH₂Cl 1564. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂Cl₂ 1565. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂F 1566. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CHF₂ 1567. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CF₃ 1568. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂OCH₃ 1569. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂OCH₂CH₃ 1570. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂OCH₂CH₃ 1571. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂CH₂SCH₃ 1572. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂C₅H₆ 1573. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂(4-ClC₅H₆) 1574. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂C═CH₂ 1575. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂(C═CH)CH₃ 1576. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂C≡CH 1577. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂COOCH₃ 1578. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₂COOCH₂CH₃ 1579. (CH₃)₃C CH₃ CH₃ CH₃ H SCH₃ 1580. (CH₃)₃C CH₃ CH₃ CH₃ H SCH₂CH₃ 1581. (CH₃)₃C CH₃ CH₃ CH₃ H SCH2COOCH3 1582. (CH₃)₃C CH₃ CH₃ CH₃ H SCH2(4-ClC5H6) 1583. (CH₃)₃C CH₃ CH₃ CH₃ H OCH₃ 1584. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₃ 1585. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H O(CH₂)₂CH₃ 1586. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH(CH₃)₂ 1587. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H O(CH₃)₃ 1588. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H O(CH₂)₂CH₃ 1589. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH(CH₃)₂ 1590. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂CH(CH₃)₂ 1591. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OC(CH₃)₂CH₂CH₃ 1592. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H O(CH₂)₄CH₃ 1593. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂Cl 1594. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂Cl 1595. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂CH₂CH₂Cl 1596. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂Cl₂ 1597. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂F 1598. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CHF₂ 1599. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CF₃ 1600. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂OCH₃ 1601. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂OCH₂CH₃ 1602. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂OCH₂CH₃ 1603. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂CH₂SCH₃ 1604. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂C₅H₆ 1605. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂(4-ClC₅H₆) 1606. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂C═CH₂ 1607. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂(C═CH)CH₃ 1608. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂C≡CH 1609. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂COOCH₃ 1610. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H OCH₂COOCH₂CH₃ 1611. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H SCH₃ 1612. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H SCH₂CH₃ 1613. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H SCH2COOCH3 1614. (CH₃)₃C CH₃CH₂ CH₃ CH₃ H SCH2(4-ClC5H6) 1615. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₃ 1616. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₃ 1617. (CH₃)₃C H CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 1618. (CH₃)₃C H CH₃CH₂ CH₃ H OCH(CH₃)₂ 1619. (CH₃)₃C H CH₃CH₂ CH₃ H O(CH₃)₃ 1620. (CH₃)₃C H CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 1621. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH(CH₃)₂ 1622. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂CH(CH₃)₂ 1623. (CH₃)₃C H CH₃CH₂ CH₃ H OC(CH₃)₂CH₂CH₃ 1624. (CH₃)₃C H CH₃CH₂ CH₃ H O(CH₂)₄CH₃ 1625. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂Cl 1626. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂Cl 1627. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂CH₂CH₂Cl 1628. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂Cl₂ 1629. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂F 1630. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CHF₂ 1631. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CF₃ 1632. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂OCH₃ 1633. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂OCH₂CH₃ 1634. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂OCH₂CH₃ 1635. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂CH₂SCH₃ 1636. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂C₅H₆ 1637. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂(4-ClC₅H₆) 1638. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂C═CH₂ 1639. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂(C═CH)CH₃ 1640. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂C≡CH 1641. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂COOCH₃ 1642. (CH₃)₃C H CH₃CH₂ CH₃ H OCH₂COOCH₂CH₃ 1643. (CH₃)₃C H CH₃CH₂ CH₃ H SCH₃ 1644. (CH₃)₃C H CH₃CH₂ CH₃ H SCH₂CH₃ 1645. (CH₃)₃C H CH₃CH₂ CH₃ H SCH2COOCH3 1646. (CH₃)₃C H CH₃CH₂ CH₃ H SCH2(4-ClC5H6) 1647. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₃ 1648. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₃ 1649. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 1650. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH(CH₃)₂ 1651. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H O(CH₃)₃ 1652. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 1653. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH(CH₃)₂ 1654. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂CH(CH₃)₂ 1655. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OC(CH₃)₂CH₂CH₃ 1656. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H O(CH₂)₄CH₃ 1657. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂Cl 1658. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂Cl 1659. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂CH₂CH₂Cl 1660. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂Cl₂ 1661. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂F 1662. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CHF₂ 1663. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CF₃ 1664. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂OCH₃ 1665. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂OCH₂CH₃ 1666. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂OCH₂CH₃ 1667. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂CH₂SCH₃ 1668. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂C₅H₆ 1669. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂(4-ClC₅H₆) 1670. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂C═CH₂ 1671. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂(C═CH)CH₃ 1672. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂C≡CH 1673. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂COOCH₃ 1674. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₂COOCH₂CH₃ 1675. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H SCH₃ 1676. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H SCH₂CH₃ 1677. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H SCH2COOCH3 1678. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H SCH2(4-ClC5H6) 1679. (CH₃)₃C CH₃ CH₃CH₂ CH₃ H OCH₃ 1680. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₃ 1681. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 1682. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH(CH₃)₂ 1683. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H O(CH₃)₃ 1684. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H O(CH₂)₂CH₃ 1685. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH(CH₃)₂ 1686. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂CH(CH₃)₂ 1687. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OC(CH₃)₂CH₂CH₃ 1688. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H O(CH₂)₄CH₃ 1689. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂Cl 1690. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂Cl 1691. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂CH₂CH₂Cl 1692. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂Cl₂ 1693. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂F 1694. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CHF₂ 1695. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CF₃ 1696. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂OCH₃ 1697. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂OCH₂CH₃ 1698. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂OCH₂CH₃ 1699. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂CH₂SCH₃ 1700. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂C₅H₆ 1701. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂(4-ClC₅H₆) 1702. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂C═CH₂ 1703. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂(C═CH)CH₃ 1704. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂C≡CH 1705. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂COOCH₃ 1706. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H OCH₂COOCH₂CH₃ 1707. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H SCH₃ 1708. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H SCH₂CH₃ 1709. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H SCH2COOCH3 1710. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ H SCH2(4-ClC5H6) 1711. (CH₃)₃C H CH₃ CH₃ Cl OCH₃ 1712. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₃ 1713. (CH₃)₃C H CH₃ CH₃ Cl O(CH₂)₂CH₃ 1714. (CH₃)₃C H CH₃ CH₃ Cl OCH(CH₃)₂ 1715. (CH₃)₃C H CH₃ CH₃ Cl O(CH₃)₃ 1716. (CH₃)₃C H CH₃ CH₃ Cl O(CH₂)₂CH₃ 1717. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH(CH₃)₂ 1718. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 1719. (CH₃)₃C H CH₃ CH₃ Cl OC(CH₃)₂CH₂CH₃ 1720. (CH₃)₃C H CH₃ CH₃ Cl O(CH₂)₄CH₃ 1721. (CH₃)₃C H CH₃ CH₃ Cl OCH₂Cl 1722. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂Cl 1723. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 1724. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂Cl₂ 1725. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂F 1726. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CHF₂ 1727. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CF₃ 1728. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂OCH₃ 1729. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂OCH₂CH₃ 1730. (CH₃)₃C H CH₃ CH₃ Cl OCH₂OCH₂CH₃ 1731. (CH₃)₃C H CH₃ CH₃ Cl OCH₂CH₂SCH₃ 1732. (CH₃)₃C H CH₃ CH₃ Cl OCH₂C₅H₆ 1733. (CH₃)₃C H CH₃ CH₃ Cl OCH₂(4-ClC₅H₆) 1734. (CH₃)₃C H CH₃ CH₃ Cl OCH₂C═CH₂ 1735. (CH₃)₃C H CH₃ CH₃ Cl OCH₂(C═CH)CH₃ 1736. (CH₃)₃C H CH₃ CH₃ Cl OCH₂C≡CH 1737. (CH₃)₃C H CH₃ CH₃ Cl OCH₂COOCH₃ 1738. (CH₃)₃C H CH₃ CH₃ Cl OCH₂COOCH₂CH₃ 1739. (CH₃)₃C H CH₃ CH₃ Cl SCH₃ 1740. (CH₃)₃C H CH₃ CH₃ Cl SCH₂CH₃ 1741. (CH₃)₃C H CH₃ CH₃ Cl SCH2COOCH3 1742. (CH₃)₃C H CH₃ CH₃ Cl SCH2(4-ClC5H6) 1743. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₃ 1744. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₃ 1745. (CH₃)₃C CH₃ CH₃ CH₃ Cl O(CH₂)₂CH₃ 1746. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH(CH₃)₂ 1747. (CH₃)₃C CH₃ CH₃ CH₃ Cl O(CH₃)₃ 1748. (CH₃)₃C CH₃ CH₃ CH₃ Cl O(CH₂)₂CH₃ 1749. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH(CH₃)₂ 1750. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 1751. (CH₃)₃C CH₃ CH₃ CH₃ Cl OC(CH₃)₂CH₂CH₃ 1752. (CH₃)₃C CH₃ CH₃ CH₃ Cl O(CH₂)₄CH₃ 1753. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂Cl 1754. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂Cl 1755. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 1756. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂Cl₂ 1757. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂F 1758. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CHF₂ 1759. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CF₃ 1760. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂OCH₃ 1761. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂OCH₂CH₃ 1762. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂OCH₂CH₃ 1763. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂CH₂SCH₃ 1764. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂C₅H₆ 1765. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂(4-ClC₅H₆) 1766. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂C═CH₂ 1767. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂(C═CH)CH₃ 1768. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂C≡CH 1769. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂COOCH₃ 1770. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₂COOCH₂CH₃ 1771. (CH₃)₃C CH₃ CH₃ CH₃ Cl SCH₃ 1772. (CH₃)₃C CH₃ CH₃ CH₃ Cl SCH₂CH₃ 1773. (CH₃)₃C CH₃ CH₃ CH₃ Cl SCH2COOCH3 1774. (CH₃)₃C CH₃ CH₃ CH₃ Cl SCH2(4-ClC5H6) 1775. (CH₃)₃C CH₃ CH₃ CH₃ Cl OCH₃ 1776. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₃ 1777. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl O(CH₂)₂CH₃ 1778. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH(CH₃)₂ 1779. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl O(CH₃)₃ 1780. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl O(CH₂)₂CH₃ 1781. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH(CH₃)₂ 1782. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 1783. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OC(CH₃)₂CH₂CH₃ 1784. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl O(CH₂)₄CH₃ 1785. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂Cl 1786. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂Cl 1787. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 1788. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂Cl₂ 1789. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂F 1790. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CHF₂ 1791. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CF₃ 1792. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂OCH₃ 1793. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂OCH₂CH₃ 1794. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂OCH₂CH₃ 1795. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂CH₂SCH₃ 1796. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂C₅H₆ 1797. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂(4-ClC₅H₆) 1798. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂C═CH₂ 1799. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂(C═CH)CH₃ 1800. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂C≡CH 1801. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂COOCH₃ 1802. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl OCH₂COOCH₂CH₃ 1803. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl SCH₃ 1804. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl SCH₂CH₃ 1805. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl SCH2COOCH3 1806. (CH₃)₃C CH₃CH₂ CH₃ CH₃ Cl SCH2(4-ClC5H6) 1807. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₃ 1808. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₃ 1809. (CH₃)₃C H CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 1810. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH(CH₃)₂ 1811. (CH₃)₃C H CH₃CH₂ CH₃ Cl O(CH₃)₃ 1812. (CH₃)₃C H CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 1813. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH(CH₃)₂ 1814. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 1815. (CH₃)₃C H CH₃CH₂ CH₃ Cl OC(CH₃)₂CH₂CH₃ 1816. (CH₃)₃C H CH₃CH₂ CH₃ Cl O(CH₂)₄CH₃ 1817. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂Cl 1818. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂Cl 1819. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 1820. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂Cl₂ 1821. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂F 1822. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CHF₂ 1823. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CF₃ 1824. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₃ 1825. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₂CH₃ 1826. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂OCH₂CH₃ 1827. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂CH₂SCH₃ 1828. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂C₅H₆ 1829. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂(4-ClC₅H₆) 1830. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂C═CH₂ 1831. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂(C═CH)CH₃ 1832. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂C≡CH 1833. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂COOCH₃ 1834. (CH₃)₃C H CH₃CH₂ CH₃ Cl OCH₂COOCH₂CH₃ 1835. (CH₃)₃C H CH₃CH₂ CH₃ Cl SCH₃ 1836. (CH₃)₃C H CH₃CH₂ CH₃ Cl SCH₂CH₃ 1837. (CH₃)₃C H CH₃CH₂ CH₃ Cl SCH2COOCH3 1838. (CH₃)₃C H CH₃CH₂ CH₃ Cl SCH2(4-ClC5H6) 1839. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₃ 1840. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₃ 1841. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 1842. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH(CH₃)₂ 1843. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl O(CH₃)₃ 1844. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 1845. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH(CH₃)₂ 1846. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 1847. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OC(CH₃)₂CH₂CH₃ 1848. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl O(CH₂)₄CH₃ 1849. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂Cl 1850. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂Cl 1851. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 1852. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂Cl₂ 1853. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂F 1854. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CHF₂ 1855. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CF₃ 1856. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₃ 1857. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₂CH₃ 1858. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂OCH₂CH₃ 1859. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂CH₂SCH₃ 1860. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂C₅H₆ 1861. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂(4-ClC₅H₆) 1862. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂C═CH₂ 1863. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂(C═CH)CH₃ 1864. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂C≡CH 1865. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂COOCH₃ 1866. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₂COOCH₂CH₃ 1867. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl SCH₃ 1868. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl SCH₂CH₃ 1869. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl SCH2COOCH3 1870. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl SCH2(4-ClC5H6) 1871. (CH₃)₃C CH₃ CH₃CH₂ CH₃ Cl OCH₃ 1872. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₃ 1873. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 1874. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH(CH₃)₂ 1875. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl O(CH₃)₃ 1876. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl O(CH₂)₂CH₃ 1877. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH(CH₃)₂ 1878. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂CH(CH₃)₂ 1879. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OC(CH₃)₂CH₂CH₃ 1880. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl O(CH₂)₄CH₃ 1881. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂Cl 1882. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂Cl 1883. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂CH₂CH₂Cl 1884. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂Cl₂ 1885. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂F 1886. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CHF₂ 1887. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CF₃ 1888. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₃ 1889. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂OCH₂CH₃ 1890. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂OCH₂CH₃ 1891. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂CH₂SCH₃ 1892. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂C₅H₆ 1893. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂(4-ClC₅H₆) 1894. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂C═CH₂ 1895. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂(C═CH)CH₃ 1896. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂C≡CH 1897. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂COOCH₃ 1898. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl OCH₂COOCH₂CH₃ 1899. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl SCH₃ 1900. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl SCH₂CH₃ 1901. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl SCH2COOCH3 1902. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ Cl SCH2(4-ClC5H6) 1903. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₃ 1904. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₃ 1905. (CH₃)₃C H CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 1906. (CH₃)₃C H CH₃ CH₃ CH₃ OCH(CH₃)₂ 1907. (CH₃)₃C H CH₃ CH₃ CH₃ O(CH₃)₃ 1908. (CH₃)₃C H CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 1909. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH(CH₃)₂ 1910. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 1911. (CH₃)₃C H CH₃ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 1912. (CH₃)₃C H CH₃ CH₃ CH₃ O(CH₂)₄CH₃ 1913. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂Cl 1914. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂Cl 1915. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 1916. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂Cl₂ 1917. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂F 1918. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CHF₂ 1919. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CF₃ 1920. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂OCH₃ 1921. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 1922. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂OCH₂CH₃ 1923. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂CH₂SCH₃ 1924. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂C₅H₆ 1925. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂(4-ClC₅H₆) 1926. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂C═CH₂ 1927. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂(C═CH)CH₃ 1928. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂C≡CH 1929. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂COOCH₃ 1930. (CH₃)₃C H CH₃ CH₃ CH₃ OCH₂COOCH₂CH₃ 1931. (CH₃)₃C H CH₃ CH₃ CH₃ SCH₃ 1932. (CH₃)₃C H CH₃ CH₃ CH₃ SCH₂CH₃ 1933. (CH₃)₃C H CH₃ CH₃ CH₃ SCH2COOCH3 1934. (CH₃)₃C H CH₃ CH₃ CH₃ SCH2(4-ClC5H6) 1935. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₃ 1936. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₃ 1937. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 1938. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH(CH₃)₂ 1939. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ O(CH₃)₃ 1940. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 1941. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH(CH₃)₂ 1942. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 1943. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 1944. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ O(CH₂)₄CH₃ 1945. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂Cl 1946. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂Cl 1947. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 1948. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂Cl₂ 1949. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂F 1950. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CHF₂ 1951. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CF₃ 1952. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂OCH₃ 1953. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 1954. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂OCH₂CH₃ 1955. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂CH₂SCH₃ 1956. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂C₅H₆ 1957. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂(4-ClC₅H₆) 1958. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂C═CH₂ 1959. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂(C═CH)CH₃ 1960. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂C≡CH 1961. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂COOCH₃ 1962. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₂COOCH₂CH₃ 1963. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ SCH₃ 1964. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ SCH₂CH₃ 1965. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ SCH2COOCH3 1966. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ SCH2(4-ClC5H6) 1967. (CH₃)₃C CH₃ CH₃ CH₃ CH₃ OCH₃ 1968. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₃ 1969. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 1970. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH(CH₃)₂ 1971. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ O(CH₃)₃ 1972. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ O(CH₂)₂CH₃ 1973. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH(CH₃)₂ 1974. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 1975. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 1976. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ O(CH₂)₄CH₃ 1977. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂Cl 1978. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂Cl 1979. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 1980. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂Cl₂ 1981. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂F 1982. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CHF₂ 1983. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CF₃ 1984. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂OCH₃ 1985. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 1986. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂OCH₂CH₃ 1987. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂CH₂SCH₃ 1988. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂C₅H₆ 1989. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂(4-ClC₅H₆) 1990. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂C═CH₂ 1991. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂(C═CH)CH₃ 1992. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂C≡CH 1993. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂COOCH₃ 1994. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ OCH₂COOCH₂CH₃ 1995. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ SCH₃ 1996. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ SCH₂CH₃ 1997. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ SCH2COOCH3 1998. (CH₃)₃C CH₃CH₂ CH₃ CH₃ CH₃ SCH2(4-ClC5H6) 1999. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₃ 2000. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₃ 2001. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 2002. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH(CH₃)₂ 2003. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ O(CH₃)₃ 2004. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 2005. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH(CH₃)₂ 2006. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 2007. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 2008. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ O(CH₂)₄CH₃ 2009. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂Cl 2010. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl 2011. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 2012. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl₂ 2013. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂F 2014. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CHF₂ 2015. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CF₃ 2016. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₃ 2017. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 2018. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂OCH₂CH₃ 2019. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂CH₂SCH₃ 2020. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂C₅H₆ 2021. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂(4-ClC₅H₆) 2022. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂C═CH₂ 2023. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂(C═CH)CH₃ 2024. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂C≡CH 2025. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂COOCH₃ 2026. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ OCH₂COOCH₂CH₃ 2027. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ SCH₃ 2028. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ SCH₂CH₃ 2029. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ SCH2COOCH3 2030. (CH₃)₃C H CH₃CH₂ CH₃ CH₃ SCH2(4-ClC5H6) 2031. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₃ 2032. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₃ 2033. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 2034. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH(CH₃)₂ 2035. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ O(CH₃)₃ 2036. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 2037. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH(CH₃)₂ 2038. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 2039. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 2040. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ O(CH₂)₄CH₃ 2041. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂Cl 2042. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl 2043. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 2044. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl₂ 2045. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂F 2046. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CHF₂ 2047. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CF₃ 2048. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₃ 2049. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 2050. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂OCH₂CH₃ 2051. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂CH₂SCH₃ 2052. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂C₅H₆ 2053. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂(4-ClC₅H₆) 2054. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂C═CH₂ 2055. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂(C═CH)CH₃ 2056. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂C≡CH 2057. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂COOCH₃ 2058. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₂COOCH₂CH₃ 2059. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ SCH₃ 2060. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ SCH₂CH₃ 2061. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ SCH2COOCH3 2062. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ SCH2(4-ClC5H6) 2063. (CH₃)₃C CH₃ CH₃CH₂ CH₃ CH₃ OCH₃ 2064. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₃ 2065. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 2066. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH(CH₃)₂ 2067. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ O(CH₃)₃ 2068. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ O(CH₂)₂CH₃ 2069. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH(CH₃)₂ 2070. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH(CH₃)₂ 2071. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OC(CH₃)₂CH₂CH₃ 2072. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ O(CH₂)₄CH₃ 2073. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂Cl 2074. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl 2075. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂CH₂CH₂Cl 2076. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂Cl₂ 2077. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂F 2078. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CHF₂ 2079. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CF₃ 2080. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₃ 2081. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂OCH₂CH₃ 2082. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂OCH₂CH₃ 2083. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂CH₂SCH₃ 2084. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂C₅H₆ 2085. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂(4-ClC₅H₆) 2086. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂C═CH₂ 2087. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂(C═CH)CH₃ 2088. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂C≡CH 2089. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂COOCH₃ 2090. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ OCH₂COOCH₂CH₃ 2091. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ SCH₃ 2092. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ SCH₂CH₃ 2093. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ SCH2COOCH3 2094. (CH₃)₃C CH₃CH₂ CH₃CH₂ CH₃ CH₃ SCH2(4-ClC5H6)

Physical property data of part of compounds provided in the present invention are shown in Table 3 below

TABLE 3 MS (ESI) Compound m/z: No. ¹H NMR (600 MHZ, CDCl3/TMS) [M + 1] 86 1.15-1.24 (m, 4H), 1.34 (s, 9H), 1.60-1.78 (m, 6H), 2.23-2.27 (m, 1H), 2.30 (s, 3H), 3.90 (s, 3H) 5.39 + 5.46 (s, 2H), 7.44-7.46 (d, 2H), 7.76-7.78 (d, 2H) 91 0.70-0.72 (t, 3H), 1.06 (s, 6H), 1.33 (s, 9H), 1.46-1.50 (q, 2H), 2.30 (s, 3H), 3.91 (s, 3H), 5.36 + 5.51 (s, 2H), 7.43-7.44 (d, 2H), 7.76-7.78 (d, 2H) 79 1.08-1.09 (d, 6H), 1.34 (s, 9H), 2.30 (s, 3H), 2.48-2.53 (m, 1H), 3.90 (s, 3H), 5.40 + 5.48 (s, 2H), 7.44-7.46 (d, 2H), 7.75-7.77 (d, 2H) 84 0.91-0.93 (m, 2H), 0.98-1.01 (m, 2H), 1.34 (s, 9H), 1.57-1.59 (m, 1H), 2.30 (s, 3H), 3.90 (s, 3H), 5.40 (s, 2H), 7.45-7.47 (d, 2H), 7.76-7.78 (d, 2H) 80 1.10 (s, 9H), 1.34 (s, 9H), 2.30 (s, 3H), 3.91 (s, 3H), 5.33 + 5.52 (s, 2H), 7.43-7.44 (d, 2H), 7.76-7.78 (d, 2H) 104 1.06-1.07 (d, 3H), 1.10-1.11 (d, 3H), 1.35 (s, 9H), 1.58-1.59 (d, 3H), 2.28 (s, 3H), 2.45-2.48 (m, 1H), 3.96 (s, 3H), 6.05-6.07 (m, 1H), 7.45-7.46 (d, 2H), 7.78-7.79 (d, 2H) 101 7.80-7.79(d, J = 6.63, 2H), 7.48-7.47 (d, J = 8.14, 2H), 6.06 (s, 1H), 3.93(s, 3H), 2.27(s, 3H), 2.00(s, 3H), 1.59-1.56(d, J = 19.54, 3H), 1.35(s, 9H) 116 0.73-0.75 (t, 3H), 1.07 (s, 3H), 1.08 (s, 3H), 1.34 (s, 9H), 1.46-1.50 (m, 2H), 1.58-1.59 (d, 3H), 2.38 (s, 3H, —CH3), 3.98 (s, 3H), 6.04-6.06 (m, 1H), 7.43-7.45 (d, 2H Hz), 7.79-7.80 (d, 2H) 105 1.12 (s, 9H), 1.34 (s, 9H), 1.57-1.58 (d, 3H), 2.28 (s, 3H), 3.98 (s, 3H), 6.03 (m, 1H), 7.43-7.45 (d, 2H), 7.76-7.78 (d, 2H) 109 0.89-0.97 (m, 4H), 1.36 (s, 9H), 1.53-1.56 (m, 1H), 1.60-1.61 (d, 3H), 2.27 (s, 3H), 3.93 (s, 3H), 6.08 (m, 1H), 7.47-7.48 (d, 2H), 7.80-7.81 (d, 2H) 236 1.18-1.30 (m, 4H), 1.33 (s, 9H), 1.48-1.50 (t, 3H), 1.60-1.74 (m, 6H), 2.18-2.22 (m, 1H), 2.34 (s, 3H, —CH₃), 4.13-4.16 (q, 2H), 5.39 (s, 2H), 6.41 (s, 1H), 7.42-7.44 (d, 2H), 7.72-7.74 (d, 2H) 241 0.70-0.73 (t, 3H), 1.04 (s, 6H), 1.33 (s, 9H), 1.45-1.48 (q, 2H), 1.48-1.51 (t, 3H), 2.34 (s, 3H), 4.14-4.17 (q, 2H), 5.40 (s, 2H), 6.40 (s, 1H), 7.42-7.43 (d, 2H), 7.73-7.75 (d, 2H) 229 1.05-1.06 (d, 6H), 1.33 (s, 9H), 1.48-1.51 (t, 3H), 2.34 (s, 3H), 2.44-2.48 (m, 1H), 4.13-4.17 (q, 2H), 5.41 (s, 2H), 6.41 (s, 1H), 7.42-7.44 (d, 2H), 7.73-7.74 (d, 2H) 234 0.89-0.91 (m, 2H), 0.94-0.96 (m, 2H), 1.34 (s, 9H), 1.48-1.51 (t, 3H), 1.54-1.57 (m, 1H), 2.34 (s, 3H), 4.13-4.17 (q, 2H), 5.41 (s, 2H), 6.39 (s, 1H), 7.43-7.45 (d, 2H), 7.73-7.75 (d, 2H) 230 1.07 (s, 9H), 1.33 (s, 9H), 1.48-1.50 (t, 3H), 2.32 (s, 3H), 4.14-4.17 (q, 2H), 5.39 (s, 2H), 6.42 (s, 1H), 7.42-7.43 (d, 2H), 7.73-7.74 (d, 2H) 254 1.03-1.04 (d, 3H), 1.07-1.08 (d, 3H), 1.34 (s, 9H), 1.48-1.51 (t, 3H), 1.50-1.51 (d, 3H), 2.32 (s, 3H, —CH₃), 2.40-2.45 (m, 1H), 4.11-4.20 (m, 2H), 5.96-5.99 (q, 1H), 6.34 (s, 1H), 7.43-7.44 (d, 2H), 7.75-7.77 (d, 2H) 266 0.72-0.75 (t, 3H), 1.04 (s, 6H), 1.34 (s, 9H), 1.43-1.48 (m, 2H), 1.48-1.50 (t, 3H), 1.50-1.51 (d, 3H), 2.32 (s, 3H), 4.12-4.20 (m, 2H), 5.94-5.96 (q, 1H), 6.36 (s, 1H), 7.42-7.44 (d, 2H), 7.76-7.78 (d, 2H) 255 1.09 (s, 9H), 1.34 (s, 9H), 1.48-1.51 (t, 3H), 1.50-1.51 (d, 3H), 2.32 (s, 3H), 4.13-4.19 (m, 2H), 5.93-5.96 (q, 1H), 6.36 (s, 1H), 7.42-7.43 (d, 2H), 7.75-7.77 (d, 2H) 259 0.86-0.93 (m, 4H), 1.36 (s, 9H), 1.48-1.50 (t, 3H), 1.51-1.52 (d, 3H), 1.51-1.53 (m, 1H), 2.31 (s, 3H), 4.13-4.19 (m, 2H), 4.11-4.18 (m, 2H), 5.97-6.00 (m, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.76-7.77 (d, 2H) 251 1.35 (s, 9H), 1.48-1.51 (t, 3H), 1.52-1.53 (d, 3H), 1.96 (s, 3H), 2.32 (s, 3H), 4.14-4.18 (m, 2H), 5.97-6.00 (q, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.76-7.77 (d, 2H) 508 1.35 (s, 9H), 1.58-1.59 (d, 3H), 2.31 (s, 3H), 3.12-3.14 (br, 1H), 3.91 (s, 3H), 4.63-4.64 (br, 2H), 5.94-5.97 (q, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.72-7.73 (d, 2H) 506 1.34 (s, 9H), 1.57-1.58 (d, 3H), 2.31 (s, 3H), 3.91 (s, 3H), 4.53-4.55 (br, 2H), 5.25-5.34 (m, 2H), 5.82-5.86 (m, 1H), 5.93-5.96 (q, 1H), 6.31 (s, 1H), 7.44-7.46 (d, 2H), 7.74-7.76 (d, 2H) 483 1.34 (s, 9H), 1.57-1.58 (d, 3H), 2.31 (s, 3H), 3.71 (s, 3H), 3.91 (s, 3H), 5.93-5.96 (q, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.73-7.74 (d, 2H) 489 0.89-0.91 (d, 6H), 1.34 (s, 9H), 1.57-1.58 (d, 3H), 1.88-1.93 (m, 1H), 2.31 (s, 3H), 3.81-3.87 (m, 2H), 3.92 (s, 3H), 5.91-5.94 (q, 1H), 6.31 (s, 1H), 7.43-7.44 (d, 2H), 7.74-7.75 (d, 2H) 488 0.89-0.92 (t, 3H), 1.34 (s, 9H), 1.35-1.38 (m, 2H, , 1.56-1.57 (d, 3H), 1.59-1.62 (m, 2H), 2.31 (s, 3H), 3.91 (s, 3H), 4.05-4.07 (m, 2H), 5.91-5.94 (q, 1H), 6.31 (s, 1H), 7.43-7.44 (d, 2H), 7.74-7.75 (d, 2H) 489 0.88-0.90 (m, 6H), 1.34 (s, 9H), 1.49-1.50 (m, 2H), 1.57-1.58 (d, 3H), 1.62-1.67 (m, 1H), 2.31 (s, 3H), 3.81-3.87 (m, 2H,), 3.92 (s, 3H), 4.07-4.11 (m, 2H), 5.92-5.94 (q, 1H), 6.31 (s, 1H), 7.43-7.44 (d, 2H), 7.74-7.75 (d, 2H) 499 1.34 (s, 9H), 1.61-1.62 (d, 3H), 2.31 (s, 3H), 3.90 (s, 3H), 4.38-4.42 (q, 2H), 5.93-5.96 (q, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.72-7.73 (d, 2H) 484 1.23-1.24 (t, 3H), 1.34 (s, 9H), 1.56-1.57 (d, 3H), 2.31 (s, 3H), 3.91 (s, 3H), 4.09-4.13 (q, 2H), 5.92-5.94 (q, 1H), 6.32 (s, 1H), 7.44-7.45 (d, 2H), 7.73-7.74 (d, 2H) 675 7.80 -7.79(d, 2H), 7.48-7.46 (d, 2H), 5.91 (s, 1H), 3.91(s, 3H), 2.32 (s, 3H), 4.13-4.19 (m, 2H), 5.93-5.96 (q, 1H), 6.36 (s, 1H), 7.42-7.43 (d, 2H), 7.75-7.77 (d, 2H) 259 0.86-0.93 (m, 4H), 1.36 (s, 9H), 1.48-1.50 (t, 3H), 1.51-1.52 (d, 3H), 1.51-1.53 (m, 1H), 2.31 (s, 3H), 4.13-4.19 (m, 2H), 4.11-4.18 (m, 2H), 5.97-6.00 (m, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.76-7.77 (d, 2H) 251 1.35 (s, 9H), 1.48-1.51 (t, 3H), 1.52-1.53 (d, 3H), 1.96 (s, 3H), 2.32 (s, 3H), 4.14-4.18 (m, 2H), 5.97-6.00 (q, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.76-7.77 (d, 2H) 508 1.35 (s, 9H), 1.58-1.59 (d, 3H), 2.31 (s, 3H), 3.12-3.14 (br, 1H), 3.91 (s, 3H), 4.63-4.64 (br, 2H), 5.94-5.97 (q, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.72-7.73 (d, 2H) 506 1.34 (s, 9H), 1.57-1.58 (d, 3H), 2.31 (s, 3H), 3.91 (s, 3H), 4.53-4.55 (br, 2H), 5.25-5.34 (m, 2H), 5.82-5.86 (m, 1H), 5.93-5.96 (q, 1H), 6.31 (s, 1H), 7.44-7.46 (d, 2H), 7.74-7.76 (d, 2H) 483 1.34 (s, 9H), 1.57-1.58 (d, 3H), 2.31 (s, 3H), 3.71 (s, 3H), 3.91 (s, 3H), 5.93-5.96 (q, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.73-7.74 (d, 2H) 489 0.89-0.91 (d, 6H), 1.34 (s, 9H), 1.57-1.58 (d, 3H), 1.88-1.93 (m, 1H), 2.31 (s, 3H), 3.81-3.87 (m, 2H), 3.92 (s, 3H), 5.91-5.94 (q, 1H), 6.31 (s, 1H), 7.43-7.44 (d, 2H), 7.74-7.75 (d, 2H) 488 0.89-0.92 (t, 3H), 1.34 (s, 9H), 1.35-1.38 (m, 2H, , 1.56-1.57 (d, 3H), 1.59-1.62 (m, 2H), 2.31 (s, 3H), 3.91 (s, 3H), 4.05-4.07 (m, 2H), 5.91-5.94 (q, 1H), 6.31 (s, 1H), 7.43-7.44 (d, 2H), 7.74-7.75 (d, 2H) 489 0.88-0.90 (m, 6H), 1.34 (s, 9H), 1.49-1.50 (m, 2H), 1.57-1.58 (d, 3H), 1.62-1.67 (m, 1H), 2.31 (s, 3H), 3.81-3.87 (m, 2H,), 3.92 (s, 3H), 4.07-4.11 (m, 2H), 5.92-5.94 (q, 1H), 6.31 (s, 1H), 7.43-7.44 (d, 2H), 7.74-7.75 (d, 2H) 499 1.34 (s, 9H), 1.61-1.62 (d, 3H), 2.31 (s, 3H), 3.90 (s, 3H), 4.38-4.42 (q, 2H), 5.93-5.96 (q, 1H), 6.32 (s, 1H), 7.45-7.46 (d, 2H), 7.72-7.73 (d, 2H) 484 1.23-1.24 (t, 3H), 1.34 (s, 9H), 1.56-1.57 (d, 3H), 2.31 (s, 3H), 3.91 (s, 3H), 4.09-4.13 (q, 2H), 5.92-5.94 (q, 1H), 6.32 (s, 1H), 7.44-7.45 (d, 2H), 7.73-7.74 (d, 2H) 675 7.80-7.79(d, 2H), 7.48-7.46 (d, 2H), 5.91 (s, 1H), 3.91(s, 3H), 3.72 (s, 3H), 2.28 (s, 3H), 1.61 (s, 3H), 1.35 (s, 9H). 676 7.80-7.79(d, 2H,), 7.47-7.46 (d, 2H), 5.91 (s, 1H), 4.14-4.10(q, 2H), 3.92(s, 3H), 2.28 (s, 3H), 1.61 (s, 3H), 1.35(s, 9H), 1.27-1.25(t, 3H). 680 7.80-7.79(d, 2H,), 7.47-7.46 (d, 2H), 5.93 (s, 1H), 4.08-4.05(q, 2H), 3.92(s, 3H), 2.28 (s, 3H), 1.72-1.66 (m, 2H), 1.45-1.39(10, 2H), 1.61 (s, 3H), 1.35 (s, 9H), 0.93-0.90 (t,s 3H), 678 7.71-7.70(d, 2H,), 7.38-7.36 (d, 2H), 5.84 (s, 1H), 3.83(s, 3H), 3.75-3.74(dd, 6.73, 2H), 2.18(s, 3H), 1.85-1.80 (m, 1H), 1.55-1.48 (d, 2H), 1.25 (s, 9H), 0.82-0.81 (d, 6H). 682 7.80-7.79(d, 2H,), 7.47-7.46 (d, 2H), 5.93 (s, 1H), 4.10-4.08(t, 2H), 3.92(s, 3H), 2.28(s, 3H), 1.65-1.64(d, 3H), 1.51-1.50 m, 1H), 1.35 (s, 9H), 0.93-0.92 (dd, 2H), 0.91-0.89(dd, 6H), 698 7.71-7.69(d, 2H), 7.38-7.36 (d, 2H), 5.87 (s, 1H), 5.79-5.73(m, 1H), 5.25-5.17(m, 2H), 4.45-4.44(d, 2H), 3.82(s, 3H), 2.18(s, 3H), 1.55-1.49(d, 3H), 1.25 (s, 9H), 692 7.72-7.71(d, 2H,), 7.39-7.38 (d, 2H), 5.87 (s, 1H), 4.22-4.12(m, 2H), 3.84(s, 3H), 3.55-3.47(m, 2H), 3.27(s, 3H), 2.20(s, 3H) 1.56-1.55 (d, 3H), 1.27(s, 9H), 700 7.69-7.68(d, 2H,), 7.38-7.37 (d, 2H), 5.87 (s, 1H), 4.55(s, 2H), 3.99(s, 3H), 2.86-2.79(m, 1H), 2.18(s, 3H), 1.48(s, 3H), 1.26(s, 9H), 691 7.78-7.77(d, 2H,), 7.48-7.47 (d, 2H), 5.96 (s, 1H), 4.41-4.39(m, 2H), 3.90(s, 3H), 2.28(s, 3H), 1.55(s, 3H), 1.35(s, 9H), 602 1.34 (s, 9H), 1.49-1.51 (t, 3H), 1.56-1.57 (d, 3H), 2.32 (s, 3H), 4.12-4.16 (m, 2H), 4.54-4.55 (br, 2H), 5.25-5.34 (m, 2H), 5.82-5.87 (m, 1H), 5.88-5.90 (q, 1H,), 6.33 (s, 1H), 7.44-7.46 (d, 2H), 7.75-7.77 (d, 2H) 604 1.35 (s, 9H), 1.50-1.52 (t, 3H), 1.57-1.58 (d, 3H), 2.32 (s, 3H), 3.11-3.13 (br, 1H), 4.12-4.17 (m, 2H), 4.64-4.65 (br, 2H), 5.88- 5.91 (q, 1H), 6.35 (s, 1H), 7.45-7.46 (d, 2H), 7.74-7.75 (d, 2H) 586 0.89-0.90 (d, 6H), 1.34 (s, 9H), 1.49-1.51 (t, 3H), 1.55-1.56 (d, 3H), 1.63-1.71 (m, 2H), 2.33 (s, 3H), 4.09-4.13 (br, 2H), 4.16-4.18 (m, 2H), 5.87-5.90 (q, 1H), 6.34 (s, 1H), 7.44-7.45 (d, 2H), 7.73-7.74 (d, 2H) 595 1.35 (s, 9H), 1.48-1.51 (t, 3H), 1.60-1.61 (d, 3H), 2.32 (s, 3H), 4.09-4.17 (m, 2H), 4.39-4.43 (q, 2H), 5.88-5.90 (q, 1H), 6.33 (s, 1H), 7.45-7.46 (d, 2H), 7.74-7.75 (d, 2H) 584 0.90-0.92 (t, 3H), 1.35 (s, 9H), 1.36-1.38 (m, 2H), 1.48-1.51 (t, 3H), 1.55-1.56 (d, 3H), 1.58-1.60 (m, 2H), 2.32 (s, 3H), 4.05-4.08 (m, 2H), 4.12-4.18 (m, 2H), 5.87-5.90 (q, 1H), 6.34 (s, 1H), 7.45-7.46 (d, 2H), 7.76-7.77 (d, 2H) 596 1.35 (s, 9H), 1.48-1.51 (t, 3H), 1.55-1.56 (d, 3H), 2.32 (s, 3H), 3.35 (s, 3H), 3.61-3.62 (t, 2H), 4.11-4.18 (m, 2.H), 4.28-4.30 (t, 2H), 5.87- 5.90 (q, 1H), 6.34 (s, 1H), 7.45-7.46 (d, 2H), 7.74-7.75 (d, 2H) 579 1.35 (s, 9H), 1.49-1.51 (t, 3H), 1.55-1.56 (d, 3H), 2.32 (s, 3H), 3.71 (s, 3H), 4.11-4.17 (m, 2H), 5.88-5.90 (q, 1H), 6.33 (s, 1H), 7.44-7.45 (d, 2H), 7.74-7.75 (d, 2H) 580 1.23-1.26 (t, 3H), 1.34 (s, 9H), 1.49-1.51 (t, 3H), 1.55-1.56 (d, 3H), 2.32 (s, 3H), 4.09-4.13 (q, 2H), 4.15-4.18 (m, 2H,), 5.87-5.90 (q, 1H), 6.34 (s, 1H), 7.44-7.46 (d, 2H), 7.75-7.77 (d, 2H) 585 0.90-0.91 (d, 6H), 3.34 (s, 9H), 1.49-3.51 (t, 3H), 1.56-1.57 (d, 3H), 1.89-1.93 (m, 1H), 2.32 (s, 3H), 3.81-3.87 (m, 2H), 4.10-4.18 (m, 2H), 5.87-5.89 (q, 1H), 6.34 (s, 1H), 7.43-7.45 (d, 2H), 7.75-7.77 (d, 2H) 1027 7.67-7.66(d, 2H,), 7.36-7.34 (d, 2H), 6.25(s, 1H), 5.77- 5.74(q, 1H), 4.09-4.07(m, 2H), 4.05-4.00(m, 2H), 2.94-2,90(m, 1H), 1.47-1.46(d, 3H), 1.41-1.38(1, 3H), 1.25(s, 9H), 1.20-1.19(d, 6H), 1.17-1.16(t, 3H). 1028 7.76-7.74(d, 2H,), 7.46-7.44 (d, 2H), 6.35(s, 1H), 5.86-5.84(q, 1H), 4.14-4.10(m, 2H), 3.71(s, 3H), 3.04-2.99(m, 1H), 1.56- 1.55(d, 3H), 1.50-1.48(t, 3H), 1.35(s, 9H), 1.30-1.29(d, 6H). 1029 7.76-7.75(d, 2H,), 7.45-7.44 (d, 2H), 6.35(s, 1H), 5.86-5.83(q, 1H), 4.20-4.10(m, 2H), 4.06-4.04(q, 2H), 3.04-2.99(m, 1H), 1.59(s, 4H), 1.56-1.55(4 3H), 1.50-1.48(t, 3H), 1.34(s, 9H), 1.30-1.28(d, 6H), 0.93-0.90(t, 3H), 1030 7.76-7.75(d, 2H,), 7.45-7.44 (d, 2H), 6.35(s, 1H), 5.86-5.83(q, 1H), 4.21-4.09(m, 2H), 3.84-3.82(q, 2H), 3.04-2.99(m, 1H), 1.93- 1.89(m, 1H), 1.56-1.55(d, 3H), 1.50-1.48(t, 3H), 1.34(s, 9H), 1.29-1.28(d, 6H), 0.91-0.90(d, 6H), 1031 7.76- 7.74(d, 2H,), 7.45-7.44 (d, 2H), 6.35(s, 1H), 5.87-5.84(q, 1H), 4,19-4.13(m, 4H), 3.57-3.55(q, 2H), 3.36(s, 3H), 3.04-2.99(m, 1H), 1.56-1.55(d, 3H), 1.50-1.47(t, 3H), 1.34(s, 9H), 1.29-1.28(d, 6H), 1032 7.76-7.75(d, 2H), 7.45-7.44 (d, 2H), 6.35(s, 1H), 5.87-5.84(q, 1H), 4.20-4.11(m, 2H), 4.10-4.07(m, 2H), 3.04-2.99(m, 1H), 1.56- 1.55(d, 3H), 1.5 l(m, 2H), 1.50-1.48(t, 3H), 1.34(s, 9H), 1.29-1.28(d, 6H), 0.90-0.89(d, J = 6.66, 6H), 1033 7.76-7.75(d, J 2H,), 7.45-7.44 (d, 2H), 6.35(s, 1H), 5.87-5.84(q, 1H), 5.26-5.17(m, 2H), 4.46-4.45(d, 2H), 4.10-4.03(m, 2H), 2.96-2.91(m, 1H), 1.49-1.48(d, 3H), 1.42-1.39(t, 3H), 1.26(s, 9H), 1.22-1.20(d, 6H), 1034 7.75-7.74(d, 2H,), 7.46-7.44 (d, 2H), 6.36(s, 1H), 5.88-5.85(q, 1H), 4.64-4.63(dd, 2H), 4.17-4.12(m, 2H), 3.04-2.99-2.90(m, 1H), 2.52-2.53(t, 1H), 1.58-1.57(d, 3H), 1.50-1.48(t, 3H), 1.35(s,9H), 1.30-1.28(d, 6H), 1035 7.75-7.74(d, 2H,), 7.46-7.44 (d, 2H), 6.36(s, 1H), 5.88-5.85(q, 1H), 4.19-4.12(m, 2H), 3.03-2.99(m, 1H), 1.94(s, 3H), 1.52-1.51 (d, 3H), 1.50-1.48(t, 3H), 1.35(s, 9H), 1.29-1.28(d, 6H), 1036 7.81-7.80(d, 2H,), 7.48-7.47 (d, 2H), 5.95-5.93(q, 1H), 3.93(s, 3H), 3.71(s, 3H), 2.29(s, 3H), 1.66(d, 3H), 1.35(s, 9H), 1037 7.72-7.70(d, 2H), 7.38-7.37 (d, 2H), 5.85-5.83(q, 1H), 4.04- 4.00(m, 2H), 3.84(s, 3H), 2.19(s, 3H), 1.57-1.56(d, 3H), 1.25(s, 9H), 1.18-1.15(t, 3H), 1038 7.79-7.78(d, 2H,), 7.49-7.47 (d, 2H), 5.96-5.94(q, 1H), 4.41- 4.40(m, 2H), 3.91(s, 3H), 2.28(s, 3H), 1.71-170(d, 3H), 1.35(s, 9H), 1039 7.79-7.78(d, 2H,), 7.49-7.47 (d, 2H), 5.96-5.94(q, 1H), 4.41- 4.40(m, 2H), 3.91(s, 3H), 2.28(s, 3H), 1.71-1.70(d, 3H), 1.35(s, 9H), 1040 7.83-7.80(d, 2H,), 7.48-7.46 (d, 2H), 5.94-5.92(q, 1H), 3.94(s, 3H), 3.85-3.83(m, 2H), 2.28(s, 3H), I.94-1.90(m, 1H), 1.67-1.66(d, 3H), 1.35(s, 9H), 0.92-0.91(t, 6H), 1041 7.81-7.80(d, 2H,), 7.47-7.46 (d, 2H), 5.94-5.92(q, 1H), 3.94(s, 3H), 2.28(s, 3H), 1.94-1.90(m, 1H), 1.66(d, 3H), 1.61-1.58 (m, 1H), 1.53-1.50(m, 2H), 1.35(s, 9H), 0.91-0.90(t, 6H). 1042 7.83-7.80(d, 2H,), 7.48-7.46 (d, 2H), 5.96-5.93(q, 1H), 5.89-5.82(m, 1H), 5.35-5.27(m, 2H), 4.54-4.53(d, 2H), 3.92(8, 3H), 2.28(s, 3H), 1.67-1.66(d, 3H), 1.35(s, 9H), 1043 7.81-7.79(d, 2H,), 7.48-7.46 (d, 2H), 5.96-5.93(q, 1H), 4.21- 4.20(m, 2H), 3.93(s, 3H), 3.57-3.56(m, 2H), 3.36(s, 3H), 2.28(s, 3H), 1.66(d, 3H), 1.35(s, 9H), 1044 7.82-7.80(d, 2H,), 7.48-7.47 (d, 2H), 6.07-6.04(q, 1H), 3.94(s, 3H), 2.28(s, 3H), 1.99(s, 3H), 1.62-1.61(d, 3H), 1.35(s, 9H), 1045 7.80-7.79(d, 2H,), 7.48-7.46(d, 2H), 5.95(s, 1H), 3.92(s, 3H), 3.71(s, 3H), 2.69-2.66(q, 3H), 1.64-1.57(d, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H). 1046 7.80-7.79(d, 2H,), 7.48-7.46(d, 2H), 5.94(s, 1H), 4.13-4.10(q, 2H), 3.92(s, 3H), 2.69-2.65(q, 3H), 1.63-1.57(d, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H). 1047 7.78-7.77(d, 2H,), 7.48-7.47(d, 2H), 5.96(s, 1H), 4.39-4.38(m, 2H), 3.90(s, 3H), 2.69-2.65(q, 3H), 1.58(s, 3H), 1.35(s, 9H), 1.27-1.25(t, 3H) 1048 7.80-7.79(d, 2H,), 7.47-7.46(d, 2H), 5.94(s, 1H), 4.07-4.05(t, 2H), 3.93(s, 3H), 2.69-2.65(q, 3H), 1.67-1.66(m, 2H), 1.61-1.59(m, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H), 1.26-1.23(m, 2H), 0.93-0.90(t, 3H), 1049 7.80-7.79(d, 2H,), 7.47-7.46(d, 2H), 5.94(s, 1H), 3.93(s, 3H), 3.84- 3.83(d, 2H), 2.69-2.65(q, 3H), 1.94-1.90(m, 1H), 1.64-1.60(d, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H), 0.92-0.91(d, 6H), 1050 7.80-7.79(d, 2H), 7.47-7.46(d, 2H), 5.94(s, 1H), 4.10-4.08(t, 2H), 3.93(s, 3H), 2.69-2.65(q, 3H), 1.64(m, 3H), 1.59-1.58(m, 2H), 1.53-1.49(q, 1H), 1.35(s, 9H), 1.30-1.27(t, 3H), 0.91-0.89(d, 6H). 1051 7.80-7.79(d, 2H,), 7.47-7.46(d, 2H), 5.96-5.95(m, 1H), 5.88-5.84 (m, 1H), 5.34-5.26(m, 2H), 4.54-4.53(4 J = 5.65, 2H), 3.91(s, 3H), 2.69-2.65 (q, 3H), 1.64(m, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H), 1052 7.80-7.79(d, 2H,), 7.47-7.46(d, 2H), 5.95(s, 1H), 4.32-4.30(m, 2H), 3.92(s, 3H), 3.57-3.56(m, 2H), 3.36(s, 3H), 2.69-2.65(q, 3H), 1.67-1.62(m, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H), 1053 7.79-7.78(d, 2H,), 7.48-7.46(d, 2H), 5.97(s, 1H), 4.14-4.08(m, 2H), 3.93(s, 3H), 2.68-2.65(m, 2H), 1,65-1.63(m, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H), 1054 7.80-7.79(d, 2H,), 7.48-7.47(d, 2H), 6.06(s, 1H), 3.94(s, 3H), 2.69- 2.65(q, 3H), 2.02-1.99(d, 3H), 1.58(m, 3H), 1.35(s, 9H), 1.26(s, 3H), 1055 7.82-7.80(d, 2H,), 7.48-7.47 (dd, 8.47, 2H), 5.91-5,88(q, 1H), 4.18-4.16(m, 2H), 3.71(s, 3H), 2.30(s, 3H), 1.64-1.63(d, 3H), 1.53-1.51(t, 3H), 1.35(s, 9H), 1056 7.82-7.81(d, 2H,), 7.48-7.46 (dd, 8.57, 2H), 5.90-5.88(q, 1H), 4.20-4.16(m, 2H), 4.13-4.11(qd, 2H), 2.30(s, 3H), 1.64-1.63(4 3H), 1.53-1.51 (t, 3H), 1.35(s, 9H), 1.27-1.25(t, 3H), 1057 7.80-7.79(d, 2H,), 7.49-7.47 (d, 2H), 5.92-5.89(q, J1H), 4.39-4.16 (m, 2H), 4.15-4.12(m, 2H), 2.30(s, 3H), 1.68-1.67(d, 3H), 1.53-1.50 (t, 3H), 1.35(s, 9H), 1058 7.82-7.81(d, 2H,), 7.48-7.46 (d, 2H), 5.90-5.87(q, 1H), 4.19- 4.17(m, 2H), 4.07-4.04(m, 2H), 2.30(s, 3H), 1.64-1.63(d, 3H), 1.59-1.58(t, 2H), 1.53-1.51(t, 3H), 1.45-1.42(1, 2H), 1.35(s, 9H), 0.93-0.91(t, 3H), 1059 7.82-7.81(d, 2H,), 7.47-7.46 (d, 2H), 5.90-5.87(q, 1H), 4.14-4.10 (q, 2H), 3.85-3.83(m, 2H), 2.30(s, 3H), 1.95-1.91(m, 1H), 1.64- 1.63(d, 3H), 1.35(s, 9H), 1.27-1.25(t, 3H), 0.93-0.92(d, 6H), 1060 7.78-7.77(d, 2H,), 7.48-7.47(d, 2H), 5.96(s, 1H), 4.39-4.38(m, 2H), 3.90(s, 3H), 2.69-2.65(q, 3H), 1.58(s, 3H), 1.35(s, 9H), 1.27-1.25(t, 3H). 1061 7.80-7.79(d, 2H,), 7.47-7.46(d, 2H), 5.94(s, 1H), 4.07-4.05(t, 2H), 3.93(s, 3H), 2.69-2.65(q, 3H), 1.67-1.66(m, 2H), 1.61-1.59 (m, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H). 1.26-1.23(m, 2H), 0.93-0.90(t,3H). 1062 7.80-7.79(d, 2H,), 7.47-7.46(d, 2H), 5.94(s, 1H), 3.93(s, 3H), 3.84-3.83(d, 2H), 2.69-2.65(q, 3H), 1.94-1.90(m, 1H), 1.64-1.60(d, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H), 0.92-0.91 (d, 6H), 1063 7.80-7.79(d, 2H,), 7.47-7.46(d, 2H), 5.94(s, 1H), 4.10-4.08 (t, 2H), 3.93(s, 3H), 2.69-2.65(q, 3H), 1.64(m, 3H), 1.59-1.58(m, 2H), 1.53-1.49(q, 1H), 1.35(s, 9H), 1.30- 1.27(t, 3H), 0.91-0.89(d, 6H). 1064 7.80-7.79(d, 2H,), 7.47-7.46(d, 2H), 5.96-5.95(m, 1H), 5.88-5.84 (m, 1H), 5.34-5.26(m, 2H), 4.54-4.53(d, 2H), 3.91(s, 3H), 2.69-2.65(q, 3H), 1.64(m, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H). 1065 7.80-7.79(d, 2R), 7.47-7.46(d, 2H), 5.95(s, 1H), 4.32-4.30(m, 2H), 3.92(s, 3H), 3.57-3.56(m, 2H), 3.36(s, 3H), 2.69-2.65 (q, 3H), 1.67-1.62 (m, 3H), 1.35(s, 9H), 1.30-1.270, 3H), 1066 7.79-7.78(d, 2H,), 7.48-7.46(d, 2H), 5.97(s, 1H), 4.14-4.08(m, 2H), 3.93(s, 3H), 2.68-2.65(m, 2H), 1.65-1.63(m, 3H), 1.35(s, 9H), 1.30-1.27(t, 3H), 1067 7.80-7.79(d, 2H,), 7.48-7.47(d, 2H), 6.06(s, 1H), 3.94 (s, 3H), 2.69-2.65 (q, 3H), 2.02-1.99(d, 3H), 1.58(m, 3H), 1.35(s, 9H), 1.26(s, 3H), 1318 0.99-1.02(t, 3H), 1.26 (s, 9H), 1.56-1.57 (d, 3H), 2.10 (s, 3H), 2.30 (s, 3H), 3.46-3.52 (m, 1H), 3.73-3.77 (m, 1H), 6.03-6.06 (q, 1H), 6.19 (s, 1H), 6.97-6.99 (4 2H), 7.25-7.27 (d, 2H) 159 408 180 438 320 438 401 410 547 398 580 426 740 446 835 398 873 454 933 440 969 468 1308 438 1742 446

The present invention further provides the preparation method of a pyrazole derivative represented by the formula stru-1, the method comprising:

wherein X is selected from halogen.

In the preparation method provided herein, preferably, the base is at least one selected from an organic base and an inorganic base; further preferably, the base is at least one selected from sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, sodium oxide, potassium hydroxide, sodium hydride, sodium alkoxide and potassium alkoxide.

In the preparation method provided herein, preferably, the acid is at least one selected from an organic acid and an inorganic acid; further preferably, the acid is at least one selected from hydrochloric acid, sulfuric acid and acetic acid.

In the preparation method provided herein, preferably, the solvent is at least one independently selected from a protic solvent and an aprotic solvent; further preferably, the solvent is at least one independently selected from acetone, methyl ethyl ketone, tetrahydrofuran, acetonitrile, N, N-dimethylformamide, toluene and chlorobenzene.

In the preparation method provided herein, the X is selected from a halogen; preferably, the X is selected from chlorine, bromine or iodine.

In the preparation method provided herein, the catalyst is at least one selected from potassium iodide, sodium iodide, and a phase transfer catalyst.

The present invention further provides an agricultural insecticide and an acaricide. The insecticide and acaricide contain a pyrazole derivative represented by the formula stru-1 with a mass percentage of 0.1-99%. The insecticide and acaricide may further contain a carrier and an auxiliary agent commonly used in the industry in addition to the pyrazole derivative represented by the formula stru-1.

The pyrazole derivative represented by the formula stru-1 provided in the present invention is suitable for pest prevention and control, particularly suitable for prevention and control of at least one of adult mites, nymphs, mite eggs, aphids and planthoppers on crops. The pyrazole derivatives are very suitable for the prevention and control of animal pests in vine plants, fruits, horticulture, agriculture, animal health, forests, storage products and the fields of materials and health.

Preferably, the pyrazole derivatives are used for the prevention and control of at least one species of Isopoda, Diplopoda, Chilopoda, Symphyla, Thysanura, Collembola, Orthoptera, Blattaria, Dermaptera, Isoptera, Phthiraptera, Thysanoptera, Heteroptera. Homoptera, Lepidoptera, Coleoptera, Hymenoptera, Diptera, Siphonaptera, Arachnida and plant parasitic nematodes.

The Isopoda, for example, Oniscus asellus, Armadillidium vulgare, Porcellio scaber.

The Diplopoda, for example, Blaniulus guttulatus.

The Chilopoda, for example, Geophilus carpophagus, Sutigera spp.

The Symphyla, for example, Scutigerella immaculate.

The Thysanura. for example, Lepisma saccharina.

The Collembola, for example, Onychiurus armatus.

The Orthoptera, for example, Acheta domestcus, Gryllotalpa spp., Locusta migratoria, Melanoplus spp., Schistocer cagregaria.

The Blattaria, for example, Blatta orientahs, Periplanet aamericana, Leucophae amaderae, Blattella germanica.

The Dermaptera, for example, Forficula auricularia.

The Isoptera, for example, Reticulitermes spp.

The Phthiraptera, for example, Pediculus humanuscorporis, Haematopinus spp., Linognathus spp., richodectes spp. and Damalinia spp.

The Thysanoptera, for example, Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella occidentalis.

The Heteroptera, for example, Eurgaster spp., Dysdercus intermedius, Piesma quadrata, Cimexlectularius, Rhodnius prolixus, Triatoma spp.

The Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis jabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp. Phorodon humui, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvatalugens. Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.

The Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocrnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocap sapomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophilap seudospretella, Cacoecia podana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.

The Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hvpera postica, Dermestes spp., Togoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus bololeucus, Gibbium psylloides, Tribohum spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.

The Hymenoptera, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.

The Diptera, for example, Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora vicina. Lucilia spp., Chrsomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Somoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyumi, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp., Lirionyza spp.

The Siphonaptera, for example, Xenopsylla cheopis, Ceratophyllus spp.

The Arachnida, for example, Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Erio phyesribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia pratiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.

The plant parasitic nematodes, including, for example, Pratylenchus spp., Radopholus similis, Ditvlenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a single crystal diffraction pattern of Compound 251.

DETAILED DESCRIPTION OF THE EMBODIMENT

The present invention is further described in combination with particular embodiments, but the present invention is not limited to these particular embodiments. Those skilled in the art should be aware that the present invention encompasses all alternatives, modifications, and equivalents that may be included within the scope of the appended claims.

I. Preparation of Compounds

Example 1 Preparation of Intermediates (1) Synthesis of intermediate 1-ethyl-3-methyl-5-pyrazolecarboxylic acid ethyl ester

154.1 g (1 mol) of intermediate A was added to a 1000 ml flask, then 500 ml of acetonitrile and 138 g of potassium carbonate were added, and then 1 mol of diethyl sulfate was added, and the system was stirred and heated to reflux until the reaction was finished in about 3 hr by thin-layer chromatography method. The system was filtered and the mother liquor was evaporated to dryness by a rotary evaporator, and the residue was distilled under a reduced pressure to give 140 g of intermediate B, with a yield of 77.0%.

(2) Synthesis of intermediate 1-ethyl-3-methyl-4-chloro-5-pyrazolecarboxylic acid ethyl ester

18.2 g (0.1 mol) of intermediate B was added to a 100 ml flask, and 50 ml of dichloroethane and 138 g of potassium carbonate were added, and then 0.11 mol of sulfonyl chloride was added. The system was stirred and heated to reflux until the reaction was finished in about 2.5 hr by thin-layer chromatography method. The mother liquor was evaporated to dryness and the residue was used in the next reaction without treatment.

(3) Synthesis of intermediate 1-ethyl-3-methyl-4-methyl-5-pyrazolecarboxylic acid ethyl ester

The intermediate D was prepared with reference to the method provided in JP2001342178A.

(4) Synthesis of intermediate 1-methyl-3-methyl-4-methyl-5-pyrazolecarboxylic acid ethyl ester

The intermediate D-1 was prepared with reference to the method provided in JP2001342178A.

(5) Synthesis of intermediate 1-methyl-3-methyl-4-chloro-5-pyrazolecarboxylic acid ethyl ester

The intermediate C-1 is prepared according to the same method as preparation of interemdicate C.

(6) Preparation of Intermediate F

Conventional procedure; The substituted aldehyde and zinc chloride at the catalytic amount were uniformly stirred in a reactor, and the substituted acyl chloride was slowly added dropwise under a cooling state. After dropwise addition, the mixture was stirred continuously for 1-2 hr at a low temperature, and warmed up to continue reaction for 5 hr, and purified by distillation under a reduced pressure.

Preparation of Intermediate Chloromethyl Acetate:

50 g (0.6 mol) of acetyl chloride was added dropwise to a mixture of 85 g paraformaldehyde and 1.75 g zinc chloride after cooled to 0° C. The dropwise addition was finished in about 2 hr, and then the reaction system was allowed to warm to room temperature for reaction for 1 hr, and then heated to 90° C. to continue reaction for 10 hr, cooled, filtered to remove solid, and then 45 g of intermediate F-1 was obtained by reduced pressure distillation.

(7) Preparation of Intermediate H

Conventional procedure: The chloro chloroformate was slowly added dropwise to the substituted alcohol and triethylamine solution under cooling state, after dropwise addition, the mixture was stirred continuously for 1-2 hr at a low temperature, and warmed up to continue reaction for 1 hr, filtered and the solvent was distilled off, and then purified by reduced pressure distillation to obtain the intermediate H.

Preparation of Intermediate H-1:

When cooled to 0° C., 71.5 g (0.5 mol) of 1-chloroethyl chloroformate was added dropwise to 40 g and 52.0 g of triethylamine in 250 ml of toluene solution. The dropwise addition was finished in about 2 hr, and then the reaction system was allowed to warm to room temperature for reaction for 1 hr, and then filtered to remove solid, to obtain 78.5 g of intermediate H-1 by reduced pressure distillation.

(8) Preparation of Intermediate TA-1

17.3 g of p-tert-butyl phenylacetonitrile was dissolved in 70 ml of anhydrous THF when the system was cooled to −5° C., equimolar amount of solid sodium methoxide was added, and then equimolar amount of intermediate B was added dropwise while stirring. When the dropwise addition was finished in 2 hr, the mixture was stirred continuously for 1.5 hr, and then warmed up to room temperature to continue stirring for 2 hr, after reaction, the THF was evaporated. The residue was dissolved in water and then neutralized with hydrochloric acid to about pH 4, extracted with ethyl acetate, dried over anhydrous sodium sulfate to evaporate ethyl acetate and obtain the intermediate TA-1, which was used in the next reaction without purification.

(9) Preparation of Intermediate TA-2

17.3 g of p-tert-butyl phenylacetonitrile was dissolved in 70 ml of anhydrous THF, when the system was cooled to −5° C., equimolar amount of solid potassium tert-butoxide was added, and then equimolar amount of intermediate C was added dropwise while stirring. When the dropwise addition was finished in 2.5 hr, the mixture was stirred continuously for 2.0 hr, and then warmed up to room temperature to continue stirring for 2 hr, after reaction, the THF was evaporated. The residue was dissolved in water and then neutralized with hydrochloric acid to about pH 4, extracted with ethyl acetate, dried over anhydrous sodium sulfate to evaporate ethyl acetate and obtain the intermediate TA-2, which was used in the next reaction without purification.

(10) Preparation of Intermediate TA-3

17.3 g of p-tert-butyl phenylacetonitrile was dissolved in 70 ml of methyl tert-butyl ether, when the system was cooled to −5° C., equimolar amount of solid potassium tert-butoxide was added, and then equimolar amount of intermediate D was added dropwise while stirring. When the dropwise addition was finished in 3.0 hr, the mixture was stirred continuously for 2.0 hr, and then warmed up to room temperature to continue stirring for 2 hr, after reaction, the methyl tert-butyl ether was evaporated. The residue was dissolved in water and then neutralized with hydrochloric acid to about pH 4, extracted with ethyl acetate, dried over anhydrous sodium sulfate to evaporate ethyl acetate and obtain the intermediate TA-3, which was used in the next reaction without purification.

(11) Preparation of Intermediate TA-4

17.3 g of p-tert-butyl phenylacetonitrile was dissolved in 70 ml of anhydrous THF, when the system was cooled to −5° C., equimolar amount of solid sodium methoxide was added, and then equimolar amount of intermediate M was added dropwise while stirring. When the dropwise addition was finished in 2 hr, the mixture was stirred continuously for 1.5 hr, and then warmed up to room temperature to continue stirring for 2 hr, after reaction, the THF was evaporated. The residue was dissolved in water and then neutralized with hydrochloric acid to about pH 4, extracted with ethyl acetate, dried over anhydrous sodium sulfate to evaporate ethyl acetate and obtain the intermediate TA-1, which was used in the next reaction without purification.

Preparation of Intermediate TA-5

17.3 g of p-tert-butyl phenylacetonitrile was dissolved in 70 ml of anhydrous THF when the system was cooled to −5° C., equimolar amount of solid potassium tert-butoxide was added, and then equimolar amount of intermediate C was added dropwise while stirring. When the dropwise addition was finished in 2.5 hr, the mixture was stirred continuously for 2.0 hr, and then warmed up to room temperature to continue stirring for 2 hr, after reaction, the THF was evaporated. The residue was dissolved in water and then neutralized with hydrochloric acid to about pH 4, extracted with ethyl acetate, dried over anhydrous sodium sulfate to evaporate ethyl acetate and obtain the intermediate TA-5, which was used in the next reaction without purification.

Preparation of Intermediate TA-6

17.3 g of p-tert-butyl phenylacetonitrile was dissolved in 70 ml of THF. when the system was cooled to −5° C., equimolar amount of solid potassium tert-butoxide was added, and then equimolar amount of intermediate D-1 was added dropwise while stirring. When the dropwise addition was finished in 3.0 hr, the mixture was stirred continuously for 2.0 hr. and then warmed up to room temperature to continue stirring for 2 hr, after reaction, MTBE was evaporated. The residue was dissolved in water and then neutralized with hydrochloric acid to about pH 4, extracted with ethyl acetate, dried over anhydrous sodium sulfate to evaporate ethyl acetate and obtain the intermediate TA-3, which was used in the next reaction without purification.

Example 2 Preparation of Target Compounds

(1) Preparation of Target Compound 226

0.31 g (0.001 mol) of intermediate TA-1 and 0.12 g (0.0011 mol) of intermediate F-1, 0.15 sodium carbonate and a catalytic amount of sodium iodide were added to 25 ml of acetonitrile, heated to reflux for 7 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate acetonitrile. The residue was purified by column chromatography to obtain 0.32 g of product, with a yield of 84%.

(2) Preparation of Target Compound 251

31 g (0.1 mol) of intermediate TA-1 and 13 g (0.11 mol) of intermediate F-2, 15 sodium carbonate and a catalytic amount of sodium iodide were added to 25 ml of acetonitrile, heated to reflux for 10 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate acetonitrile. The residue was purified by column chromatography to obtain 35.1 g of product, with a yield of 89%.

(3) Preparation of Target Compound 259

0.31 g (0.001 mol) of intermediate TA-1 and 0.13 g (0.0011 mol) of intermediate F-3, 0.15 sodium carbonate and a catalytic amount of sodium iodide were added to 25 ml of acetonitrile, heated to reflux for 12 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate acetonitrile. The residue was purified by column chromatography to obtain 0.28 g of product, with a yield of 66%.

(4) Preparation of Target Compound 326

0.34 g (0.001 mol) of intermediate TA-2 and 0.13 g (0.0011 mol) of intermediate F-2, 0.15 sodium carbonate and a catalytic amount of sodium iodide were added to 25 N, N-Dimethylformamide, heated to 70° C. to react for 4 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate the solvent under a reduced pressure. The residue was purified by column chromatography to obtain 0.24 g of product, with a yield of 56%.

(5) Preparation of Target Compound 401

0.32 g (0.001 mol) of intermediate TA-2 and 0.13 g (0.0011 mol) of intermediate F-2, 0.15 sodium carbonate and a catalytic amount of sodium iodide were added to 25 ml of acetonitrile, heated to reflux for 11 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate the solvent under a reduced pressure. The residue was purified by column chromatography to obtain 0.29 g of product, with a yield of 71%.

(6) Preparation of Target Compound 105

0.33 g (0.001 mol) of intermediate TA-5 and 0.18 g (0.0011 mol) of intermediate F-4, 0.15 sodium carbonate and a catalytic amount of sodium iodide were added to 25 ml of acetonitrile, heated to reflux for 11 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate acetonitrile. The residue was purified by column chromatography to obtain 0.25 g of product, with a yield of 55%.

(7) Preparation of Target Compound 4

0.295 g (0.1 mol) of intermediate TA-4 and 0.15 g (0.11 mol) of intermediate F-6, 0.15 sodium carbonate and a catalytic amount of sodium iodide were added to 25 ml of acetonitrile, heated to reflux for 5 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate acetonitrile. The residue was purified by column chromatography to obtain 0.31 g of product, with a yield of 78%.

(8) Preparation of Target Compound 91

0.33 g (0.1 mol) of intermediate TA-5 and 0.18 g (0.11 mol) of intermediate F-4, 0.15 sodium carbonate and a catalytic amount of sodium iodide were added to 25 ml of acetonitrile, heated to reflux for 11 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate acetonitrile. The residue was purified by column chromatography to obtain 0.25 g of product, with a yield of 55%.

(9) Preparation of Target Compound 548

0.31 g (0.001 mol) of intermediate TA-1 and 0.16 g (0.0011 mol) of intermediate H-1, 0.15 sodium carbonate and a catalytic amount of sodium iodide were added to 25 ml of acetonitrile, heated to reflux for 6 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate acetonitrile. The residue was purified by column chromatography to obtain 0.33 g of product, with a yield of 78%.

(10) Preparation of Target Compound 739

0.34 g (0.001 mol) of intermediate TA-2 and 0.13 g (0.0011 mol) of intermediate H-2, 0.15 potassium carbonate and a catalytic amount of sodium iodide were added to 25 N, N-Dimethylformamide, heated to 70° C. to react for 5 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate the solvent under a reduced pressure. The residue was purified by column chromatography to obtain 0.28 g of product, with a yield of 65%.

(11) Preparation of Target Compound 835

0.31 g (0.001 mol) of intermediate TA-6 and 0.13 g of intermediate H-3, 0.15 potassium carbonate and a catalytic amount of sodium iodide were added to 25 ml of THF, heated to reflux for 10 hr, when the reaction was finished by thin-layer chromatography method, the system was cooled to room temperature to filter solid and evaporate acetonitrile. The residue was purified by column chromatography to obtain 0.25 g of product, with a yield of 61%.

II. Preparation of Reagents

Reagents were prepared according to a mass ratio in the following embodiments.

Example 3. 30% Suspension

Compound 251 30% Ethylene glycol 10% Nonylphenol polyglycol ether  6% Sodium lignosulfonate 10% Carboxymethyl cellulose  1% 37% formaldehyde solution   0.7% 75% silicone oil emulsion   0.8% Water added to 100%

The compound 251 was fully mixed with other components, to obtain 30% suspension. The 30% suspension could be diluted with water to obtain diluent at any concentration.

Example 4. 30% Emulsion

Compound 548 30% Phosphorous acid 10% Ethoxylated triglyceride 15% Toluene added to 100%

Phosphorous acid was dissolved in toluene, then the compound 548 and ethoxylated triglyceride were added to obtain a transparent solution, i.e. 30% emulsion.

Example 5. 60% Wettable Powder

Compound 91 60% Sodium dodecylnaphthalene sulfonate  2% Sodium lignosulfonate  9% Diatomite added to 100%

The compound 91, sodium dodecylnaphthalene sulfonate, sodium lignosulfonate and diatomite were mixed together, and pulverized in a pulverizer until particles reached the standard, to obtain 60% wettable powder.

III. Biological Activity Assay Example 6. Activity Assay of Eggs of Tetranychus Cinnabarinus

According to the solubility of the test compound, the crude drug was dissolved in N N-dimethylformamide, and then prepared into a test solution of the desired concentration with 1‰ Tween 80 aqueous solution. The content of N. N-dimethylformamide in the solution should not exceed 10%.

Spray method. The broad bean leaves with petioles were cut and inserted into a bottle with water. A certain number of female mites were placed, 24h later, adult mites were removed, and spray treatment was performed in 24 h. The experiment was repeated three times, and a blank control was set, and placed to an observation room (26±2° C., humidity 70%˜80%, 16h light per day) for culture. When the blank control group was incubated, the results were investigated. The non-incubated ones were used as death for investigation.

According to the above method, the activity assay found that the ovicidal activity was equal to or higher than 90% at the concentration of 5 mg/L for the compounds 1-17, 26-72, 76-92, 101-117, 151-167, 176-192, 226-242, 251-267, 301-317, 326-342, 376-392, 401-417, 451-454, 456, 457, 458, 460, 467, 468, 471, 474, 476, 477, 480, 481, 483-486, 488, 489, 490, 492, 494, 499, 500, 503, 506, 508, 509, 512, 513, 574-548, 549, 550, 552, 553, 554, 556, 558, 563, 564, 567, 570, 572, 573, 576, 577, 579-582, 584, 585, 586, 588, 590, 595, 596, 599, 606, 602, 604, 606, 608, 609, 643-646, 648, 649, 650, 652, 654, 659, 660, 663, 666, 668, 669, 972, 673, 675-678, 680, 681, 682, 684, 691, 692, 695, 698, 700, 701, 704, 705, 739-742, 744, 745, 746, 748, 750, 755, 757, 759, 762, 764, 765, 768, 769, 771-774, 776, 777, 778, 780, 782, 787, 788, 791, 794, 796, 797, 801, 835-838, 840, 841, 842, 844, 846, 851, 853, 855, 858, 860, 862, 864, 865, 867-870, 872, 873, 874, 876, 878, 883, 884, 887, 890, 892, 894, 896, 897, 931-934, 936, 937, 938, 940, 942, 947, 948, 951, 956, 958, 961, 960, 963-966, 968, 969, 970, 972, 974, 978, 980, 986, 988, 983, 989, 992, 993, 1158, 1172, 1293, 1318, 1323, 1468; while the ovicidal activity of compounds 8-1, 8-2, 8-3, 8-4 disclosed in PCT patent application WO 01/68589 was less than 30% at a concentration of 5 mg/L.

According to the above method, the activity assay found that the ovicidal activity was equal to or higher than 90% at the concentration of 2 mg/L for the compounds 230, 234, 226, 227, 251, 252, 254, 255, 259, 301, 302, 305, 309, 326, 327, 401, 402, 409, 405, 547, 548, 549, 550, 553, 570, 579, 580, 585, 602, 771, 772, 780, 931, 932, 933, 940, 937, 963, 964 and 969; while the ovicidal activity of compounds 8-1, 8-2, 8-3, 8-4 disclosed in PCT patent application WO01/68589 was 0% at a concentration of 2 mg/L.

According to the above method, parallel determination of ovicidal activity was performed for the compounds 226, 227, 230, 234, 251, 252, 254, 255, 301, 302, 547, 585, 771, 772, 931, 932 and 937 of the present invention and the compounds 8-1, 8-2, 8-3, 8-4 disclosed in PCT patent application WO01/68589. The results were shown in Table 4.

TABLE 4 Compound Concentration (mg/L) Death rate (%) 226 2 100 227 2 97 230 2 100 234 2 100 241 2 100 251 2 100 252 2 100 254 2 99 255 2 96 301 2 95 302 2 97 547 2 100 585 2 100 675 2 100 771 2 100 772 2 100 931 2 98 932 2 97 937 2 100 8-1 2 0 8-2 2 0 8-3 2 0 8-4 2 0

Example 7 Activity Assay of Adult Tetranychus cinnabarnnus

According to the solubility of the test compound, the crude drug was dissolved in N, N-dimethlfornamide, and then prepared into a test solution of the desired concentration with 1‰ Tween 80 aqueous solution. The content of N,N-dimethylformamide in the solution should not exceed 10%.

Two euphylla bean seedlings were taken, after inoculated with adult Tetranychus cinnabarinus and the base number was investigated, whole plants were sprayed with a hand-held sprayer. The experiment was repeated three times for each treatment, after treatment, placed in a standard observation room after treatment, to investigate the survival number of mites in 48 hand calculate the death rate.

According to the above method, the activity assay found that the adult mite-killing activity was equal to or higher than 90% at the concentration of 2.5 mg/L for the compounds 1-17, 26-72, 76-92 101-117, 151-167, 176-192, 226-242, 251-267, 301-317, 326-342, 376-392, 401-417, 451-454, 456, 457, 458, 460, 467, 468, 471, 474, 476, 477, 480, 481, 483-486, 488, 489, 490, 492, 494, 499, 500, 503, 506, 508, 509, 512, 513, 574-548, 549, 550, 552, 553, 554, 556, 558, 563, 564, 567, 570, 572, 573, 576, 577, 579-582, 584, 585, 586, 588, 590, 595, 596, 599, 606, 602, 604, 606, 608, 609, 643-646, 648, 649, 650, 652, 654, 659, 660, 663, 666, 668, 669, 972, 673, 675-678, 680, 681, 682, 684, 691, 692, 695, 698, 700, 701, 704, 705, 739-742, 744, 745, 746, 748, 750, 755, 757, 759, 762, 764, 765, 768, 769, 771-774, 776, 777, 778, 780, 782, 787, 788, 791, 794, 796, 797, 801, 835-838, 840, 841, 842, 844, 846, 851, 853, 855, 858, 860, 862, 864, 865, 867-870, 872, 873, 874, 876, 878, 883, 884, 887, 890, 892, 894, 896, 897, 931-934, 936, 937, 938, 940, 942, 947, 948, 951, 956, 958, 961, 960, 963-966, 968, 969, 970, 972, 974, 978, 980, 986, 988, 983, 989, 992, 993, 1158, 1172, 1293, 1318, 1323, 1468; while the adult mite-killing activity of compounds 8-1, 8-2, 8-3, 8-4 disclosed in PCT patent application WO 01/68589 was less than 80% at a concentration of 2.5 mg/L.

According to the above method, the activity assay found that the adult mite-killing activity was equal to or higher than 90% at the concentration of 1.25 mg/L for the compounds 230, 234, 226, 227, 251, 252, 254, 255, 259, 301, 302, 305, 309, 326, 327, 401, 402, 409, 405, 547, 548, 549, 550, 553, 570, 579, 580, 585, 602, 771, 772, 780, 931, 932, 933, 940, 937, 963, 964 and 969; while the adult mite-killing activity of compounds 8-1, 8-2, 8-3, 8-4 disclosed in PCT patent application WO 01/68589 was less than 50% at a concentration of 1.25 mg/L.

According to the above method, parallel determination of adult mite-killing activity was performed for the compounds 226, 227, 230, 234, 251, 252, 254, 255, 301, 302, 547, 585, 771, 772, 931, 932 and 937 of the present invention and the compounds 8-1, 8-2, 8-3, 8-4 disclosed in PCT patent application WO01/68589. The results were shown in Table 5.

TABLE 5 Compound Concentration (mg/L) Death rate (%) 226 1.25 96 227 1.25 98 230 1.25 100 234 1.25 100 241 1.25 100 251 1.25 100 252 1.25 100 254 1.25 97 255 1.25 95 301 1.25 90 302 1.25 96 547 1.25 100 585 1.25 100 771 1.25 100 772 1.25 100 931 1.25 95 932 1.25 90 937 1.25 100 8-1 1.25 45 8-2 1.25 30 8-3 1.25 45 8-4 1.25 50

Example 8 Activity Assay of Tetranychus cinnabarinus Nymphs

According to the solubility of the test compound, the crude drug was dissolved in N, N-dimethylformamide, and then prepared into a test solution of the desired concentration with 1‰ Tween 80 aqueous solution. The content of N,N-dimethylformamide in the solution should not exceed 10%.

The broad bean leaves with petioles were cut and inserted into a small bottle with water. A certain number of brightly colored, active female adult mites were placed, 24h later, adult mites were removed, and leaves with insufficient eggs were removed. When eggs were hatched and grew into nymphs, spray treatment was performed. The experiment was repeated three times, and a blank control was set, and placed to an observation room (26±2° C., humidity 70%˜80%, 16h light per day) for culture. 48 h later, the results were investigated. The nymphs were gently touched during investigation, and if no response, they were regarded as deaths.

According to the above method, the activity assay found that the nymph-killing activity was equal to or higher than 95% at the concentration of 2.5 mg/L for the compounds 1-17 26-72, 76-92, 101-117, 151-167, 176-192, 226-242, 251-267, 301-317, 326-342, 376-392, 401-417, 451-454, 456, 457, 458, 460, 467, 468, 471, 474, 476, 477, 480, 481, 483, 486, 488, 489, 490, 492, 494, 499 500 503, 506, 508, 509, 512, 513, 574-548, 549, 550, 552, 553, 554, 556, 558, 563, 564, 567, 570, 572, 573, 576, 577, 579-582, 584, 585, 586, 588, 590, 595, 596, 599, 606, 602, 604, 606, 608, 609, 643-646, 648, 649, 650, 652, 654, 659, 660, 663, 666, 668, 669, 972, 673, 675-678, 680, 681, 682, 684, 691, 692, 695, 698, 700, 701, 704, 705, 739-742, 744, 745, 746, 748, 750, 755, 757, 759, 762, 764, 765, 768, 769, 771-774, 776, 777, 778, 780, 782, 787, 788, 791, 794, 796, 797, 801, 835-838, 840, 841, 842, 844, 846, 851, 853, 855, 858, 860, 862, 864, 865, 867-870, 872, 873, 874, 876, 878, 883, 884, 887, 890, 892, 894, 896, 897, 931-934, 936, 937, 938, 940, 942, 947, 948, 951, 956, 958, 961, 960, 963-966, 968, 969, 970, 972, 974, 978, 980, 986, 988, 983, 989, 992, 993, 1158, 1172, 1293, 1318, 1323, 1468. while the nymph-killing activity of compounds 8-1, 8-2, 8-3, 8-4 disclosed in PCT patent application WO01/68589 was less than 80% at a concentration of 2.5 mg/L.

According to the above method, the activity assay found that the nymph-killing activity was equal to or higher than 90% at the concentration of 2 mg/L for the compounds 230, 234. 226, 227, 251, 252, 254, 255, 259, 301, 302, 305, 309, 326, 327, 401, 402, 409, 405, 547, 548, 549, 550, 553, 570, 579, 580, 585, 602, 771, 772, 780, 931, 932, 933, 940, 937, 963, 964 and 969 while the nymph-killing activity of compounds 8-1, 8-2, 8-3, 8-4 disclosed in PCT patent application WO01/68589 was less than 30% at a concentration of 0.5 mg/L.

According to the above method, parallel determination of nymph-killing activity was performed for the compounds 226, 227, 230, 234, 251, 252, 254, 255, 301, 302, 547, 585, 771, 772, 931, 932 and 937 of the present invention and the compounds 8-1, 8-2, 8-3, 8-4 disclosed in PCT patent application WO01/68589. The results were shown in Table 6.

TABLE 6 Compound Concentration (mg/L) Death rate (%) 226 0.5 90 227 0.5 94 230 0.5 98 234 0.5 96 241 0.5 100 251 0.5 100 252 0.5 100 254 0.5 96 255 0.5 95 301 0.5 90 302 0.5 96 547 0.5 93 585 0.5 96 675 0.5 675 771 0.5 95 772 0.5 90 931 0.5 95 937 0.5 90 937 0.5 93 8-1 0.5 25 8-2 0.5 0 8-3 0.5 30 8-4 0.5 15 

1. A pyrazole derivative having the following formula stru-1:

wherein: R1, R2, R3, R4, R5 are independently selected from hydrogen, halogen, nitro, nitrile, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio, C₁-C₂₀ alkylsulfoxide, C₁-C₂₀ alkylsulfone, C₁-C₂₀ alkylsulfonate, C₁-C₂₀ alkyl carboxylic ester, C₁-C₂₀ alkyl acyl, C₁-C₂₀ haloalkyl acyl: R6 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone; R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₁-C₂₀ alkoxymethylene; R8 is selected from hydrogen, C₁-C₂ alkyl, C₁-C₂ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxymethylene, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone; R9 is selected from hydrogen, halogen, nitro, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio, C₁-C₂₀ alkylsulfone, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio and C₁-C₂₀ alkylsulfone; L is selected from oxygen, sulfur, methylene, nitrogen; Q is selected from oxygen, sulfur; R10 is selected from hydrogen, halogen, nitro, C₁-C₂ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₂-C₂₀ alkenyl, C₂-C₂₀ haloalkenyl, C₂-C₂₀ alkynyl, C₂-C₂₀ haloalkynyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio, C₁-C₂₀ haloalkylthio, C₁-C₂₀ alkyl carboxylic ester, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio and C₁-C₂₀ haloalkylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₂₀ alkyl, C₁-C₂₀ haloalkyl, C₃-C₂₀ cycloalkyl, C₃-C₂₀ halocycloalkyl, C₁-C₂₀ alkoxy, C₁-C₂₀ haloalkoxy, C₁-C₂₀ alkylthio and C₁-C₂₀ haloalkylthio.
 2. The pyrazole derivative according to claim 1, wherein in the formula stru-1: R1, R2, R3, R4, R5 are independently selected from hydrogen, halogen, nitro, nitrile, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₂-C₁₀ alkenyl, C₂-C₁₀ haloalkenyl, C₂-C₁₀ alkynyl, C₂-C₁₀haloalkynyl, C₁-C₁₁ alkoxy, C₁-C₁₁ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio, C₁-C₁₀ alkylsulfoxide, C₁-C₁₀ alkylsulfone, C₁-C₁₀ alkylsulfonate, C₁-C₁₀ alkyl carboxylic ester, C₁-C₁₀ alkyl acyl, C₁-C₁₁ haloalkyl acyl; R6 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₂-C₁₀ alkenyl, C₂-C₁₀ haloalkenyl, C₂-C₁₀ alkynyl, C₂-C₁₀ haloalkynyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone; R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₁-C₁₀ alkoxymethylene; R8 is selected from hydrogen, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxymethylene, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₁ haloalkylthio and C₁-C₁₀ alkylsulfone; R9 is selected from hydrogen, halogen, nitro, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁ halocycloalkyl, C₂-C₁₀ alkenyl, C₂-C₁₀ haloalkenyl, C₂-C₁₀ alkynyl, C₂-C₁₀ haloalkynyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio, C₁-C₁₀ alkylsulfone, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₁ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀alkylthio, C₁-C₁₀ haloalkylthio and C₁-C₁₀ alkylsulfone; L is selected from oxygen, sulfur, methylene, nitrogen; Q is selected from oxygen, sulfur; R10 is selected from hydrogen, halogen, nitro, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₂-C₁₀ alkenyl, C₂-C₁₀ haloalkenyl, C₂-C₁₀ alkynyl, C₂-C₁₀ haloalkynyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio, C₁-C₁₀ haloalkylthio, C₁-C₁₀ alkyl carboxylic ester, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₁ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀ alkylthio and C₁-C₁₀ haloalkylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₁₀ alkyl, C₁-C₁₀ haloalkyl, C₃-C₁₀ cycloalkyl, C₃-C₁₀ halocycloalkyl, C₁-C₁₀ alkoxy, C₁-C₁₀ haloalkoxy, C₁-C₁₀alkylthio and C₁-C₁₀ haloalkylthio.
 3. The pyrazole derivative according to claim 2, wherein in the formula stru-1: R1, R2, R3, R4, R5 are independently selected from hydrogen, halogen, nitro, nitrile, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ alkylsulfoxide, C₁-C₆ alkylsulfone, C₁-C₆ alkylsulfonate, C₁-C₆ alkyl carboxylic ester, C₁-C₆ alkylacyl, C₁-C₆ haloalkyl acyl; R6 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone; R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₁-C₆ alkoxymethylene; R8 is selected from hydrogen, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxymethylene, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone; R9 is selected from hydrogen, halogen, nitro, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ alkylsulfone, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio and C₁-C₆ alkylsulfone; L is selected from oxygen, sulfur, methylene, nitrogen; Q is selected from oxygen, sulfur; R10 is selected from hydrogen, halogen, nitro, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ alkyl carboxylic ester, phenyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio and C₁-C₆ haloalkylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, halogen, nitro, cyano, C₁-C₆ alkyl, C₁-C₆ haloalkyl, C₃-C₆ cycloalkyl, C₃-C₆ halocycloalkyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio and C₁-C₆ haloalkylthio.
 4. The pyrazole derivative according to claim 3, wherein in the formula stru-1: R1, R2, R3, R4, R5 are independently selected from hydrogen, fluorine, chlorine, bromine, nitro, nitrile, methyl, ethyl, isopropyl, tert-butyl, trifluoromethyl, methoxy, ethoxy, trifluoromethoxy, difluoromethoxy, difluoroethoxy, methylthio, trifluoromethylthio, trifluoroethylthio, methylsulfonyl, methylsulfonate; R6 is selected from hydrogen, fluorine, chlorine, bromine, nitro, nitrile, methyl, ethyl, isopropyl, cyclopropyl, methoxy, ethoxy, trifluoromethyl, difluoromethyl, p-chlorophenyl, p-fluorophenyl; R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₅ alkyl, C₁-C₅ haloalkyl, C₁-C₅ alkoxymethylene; R8 is selected from hydrogen, methyl, ethyl, monofluoromethyl, difluoromethyl, trifluoromethyl, methoxymethylene, ethoxymethylene; R9 is selected from hydrogen, fluorine, chlorine, bromine, nitro, methyl, ethyl, propyl, isopropyl, difluoromethyl, cyclopropyl, methylthiomethylene, phenyl, p-chlorophenyl, p-fluorophenyl, benzyl; L is selected from oxygen, sulfur, methylene, nitrogen; Q is selected from oxygen, sulfur; R10 is selected from hydrogen, fluorine, chlorine, nitro, C₁-C₆ alkyl, C₃-C₆ cycloalkyl, C₃-C₆ haloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ methyl alkyl carboxylate, C₁-C₆ ethyl carboxylic acid ethyl ester, phenyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, trifluoroethoxy, and methylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, trifluoroethoxy, and methylthio.
 5. The pyrazole derivative according to claim 4, wherein in the formula stru-1: R1, R2, R3, R4, R5 are independently selected from hydrogen, fluorine, chlorine, bromine, nitro, nitrile, methyl, ethyl, isopropyl, tert-butyl, trifluoromethyl, methoxy, ethoxy, trifluoromethoxy, difluoromethoxy, difluoroethoxy, methylthio, trifluoromethylthio, trifluoroethylthio, methylsulfonyl, methylsulfonate; R6 is selected from hydrogen, fluorine, chlorine, bromine, nitro, nitrile, methyl, ethyl, isopropyl, cyclopropyl, trifluoromethyl, difluoromethyl, methoxy, ethoxy, p-chlorophenyl, p-fluorophenyl; R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₅ alkyl, C₁-C₅ haloalkyl, C₁-C₅ alkoxymethylene; R8 is selected from methyl, ethyl; R9 is selected from hydrogen, fluorine, chlorine, bromine, nitro, methyl, ethyl, propyl, isopropyl, difluoromethyl, cyclopropyl, methylthiomethylene, phenyl, p-chlorophenyl, p-fluorophenyl, benzyl; L is selected from oxygen, sulfur, methylene; Q is selected from oxygen, sulfur; R10 is selected from hydrogen, fluorine, chlorine, nitro, C₁-C₆ alkyl, C₃-C₆ cycloalkyl, C₃-C₆ haloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ methyl alkyl carboxylate, C₁-C₆ ethyl carboxylic acid ethyl ester, phenyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, trifluoroethoxy, and methylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, trifluoroethoxy, and methylthio.
 6. The pyrazole derivative according to claim 4, wherein in the formula stru-1: R1, R2, R4, R5 are selected from hydrogen R3 is selected from t-butyl; R6 is selected from hydrogen, fluorine, chlorine, bromine, nitro, nitrile, methyl, ethyl, isopropyl, cyclopropyl, trifluoromethyl, difluoromethyl, methoxy, ethoxy, p-chlorophenyl, p-fluorophenyl; R7 is selected from hydrogen, halogen, nitro, nitrile, C₁-C₅ alkyl, C₁-C₅ haloalkyl, C₁-C₅ alkoxymethylene; R8 is selected from methyl, ethyl; R9 is selected from hydrogen, fluorine, chlorine, bromine, nitro, methyl, ethyl, propyl, isopropyl, difluoromethyl, cyclopropyl, methylthiomethylene, phenyl, p-chlorophenyl, p-fluorophenyl, benzyl; L is selected from oxygen, sulfur, methylene; Q is selected from oxygen, sulfur; R10 is selected from hydrogen, fluorine, chlorine, nitro, C₁-C₆ alkyl, C₃-C₆ cycloalkyl, C₃-C₆ haloalkyl, C₂-C₆ alkenyl, C₂-C₆ haloalkenyl, C₂-C₆ alkynyl, C₂-C₆ haloalkynyl, C₁-C₆ alkoxy, C₁-C₆ haloalkoxy, C₁-C₆ alkylthio, C₁-C₆ haloalkylthio, C₁-C₆ methyl alkyl carboxylate, C₁-C₆ ethyl carboxylic acid ethyl ester, at least one substituted phenyl selected from the group consisting of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, trifluoroethoxy, and methylthio, pyridyl, pyrazolyl, thienyl, furyl or thiazolyl substituted by at least one of hydrogen, fluorine, chlorine, bromine, nitro, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, trifluoroethoxy, and methylthio.
 7. The pyrazole derivative according to claim 4, wherein the pyrazole derivative is selected from at least one of the compounds represented by the following structural formula:


8. The pyrazole derivative according to claim 1, wherein the pyrazole derivative represented by the formula stru-1 comprises at least one selected from the group consisting of an E-type pyrazole derivative and a Z-type pyrazole derivative.
 9. A preparation method of a pyrazole derivative represented by the formula stru-1, comprising:

wherein the X is selected from halogen.
 10. The preparation method according to claim 9, wherein: The base is at least one selected from an organic base and an inorganic base, the acid is at least one selected from an organic acid and an inorganic acid, the solvent is at least one independently selected from a protic solvent and an aprotic solvent, and the catalyst is at least one selected from potassium iodide, sodium iodide, and a phase transfer catalyst.
 11. The preparation method according to claim 10, wherein: the X is selected from chlorine, bromine or iodine, the base is at least one selected from sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, sodium oxide, potassium hydroxide, sodium hydride, sodium alkoxide and potassium alkoxide, the acid is at least one selected from hydrochloric acid, sulfuric acid and acetic acid, and the solvent is at least one independently selected from acetone, methyl ethyl ketone, tetrahydrofuran, acetonitrile, N, N-dimethylformamide, toluene and chlorobenzene.
 12. Applications of a pyrazole derivative represented by the formula stru-1 of claim 1, wherein the pyrazole derivative is used for prevention and control of pests.
 13. The applications of pyrazole derivative according to claim 12, wherein the pyrazole derivative is used for the prevention and control of at least one species of Isopoda, Diplopoda, Chilopoda, Symphyla, Thysanura, Collembola, Orthoptera, Blattaria, Dermaptera, Isoptera, Phthiraptera, Thysanoptera, Heteroptera, Homoptera, Lepidoptera, Coleoptera, Hymenoptera, Diptera, Siphonaptera, Arachnida and plant parasitic nematodes.
 14. The applications of pyrazole derivative according to claim 13, wherein the plant parasitic nematode is at least one species selected from Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.
 15. The applications of pyrazole derivative according to claim 12, wherein the pyrazole derivative is used for prevention and control of at least one of adult mites, nymphs, mite eggs, aphids and planthoppers on crops.
 16. An agricultural insecticide and acaricide, wherein the insecticide and acaricide contain a compound represented by the formula stru-1 of claim 1 with a mass percentage of 0.1˜99%. 